Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials

doi:10.1039/c8cs00684a

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	Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials
	Lin, YM ; Sun, XY ; Su, DS ; Centi, G 3,4; Perathoner, S 5
刊名	CHEMICAL SOCIETY REVIEWS
	2018-11-21
卷号	47 期号:22 页码:8438-8473
ISSN号	0306-0012
DOI	10.1039/c8cs00684a
英文摘要	Hybrid sp(2)/sp(3) nanocarbons, in particular sp(3)-hybridized ultra-dispersed nanodiamonds and derivative materials, such as the sp(3)/sp(2)-hybridized bucky nanodiamonds and sp(2)-hybridized onion-like carbons, represent a rather interesting class of catalysts still under consideration. Their characteristics, properties and catalytic reactivity are presented, with an analysis of the state-of-the-art of their use in gas- and liquid-phase reactions, including photo- and electro-catalysis. It is remarked that intrinsic differences exist between these and other nanostructured carbon catalysts. The analysis shows how different features make nanocarbons unique with respect to other types of catalysts and are the bases for an advanced design of nanocarbon-type catalysts. The aspects discussed regard the presence of hybrid sp(2)/sp(3) configurations, nano-engineering related to the role of defects and vacancies in their catalytic behaviour, the creation of active sites by modification in the charge density at carbon atoms or C-C bonds, the generation of strained C-C bonds by curvature and other mechanisms, and the formation of semiconducting areas and defect sites at the interface with supported nanoparticles. The advanced strategies for identifying and quantifying active sites of carbon catalysts are highlighted.
学科主题	Chemistry, Multidisciplinary
语种	英语
WOS记录号	WOS:000449968700008
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/79816]
专题	金属研究所_中国科学院金属研究所
作者单位	1.Max Planck Inst Chem Energiekonvers, Stiftstr 34-36, D-45470 Mulheim, Germany 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian, Peoples R China 4.Univ Messina, ERIC Aisbl, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy 5.CASPE INSTM, Depts MIFT Ind Chem, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy 6.Univ Messina, Depts ChiBioFarAm Ind Chem, Vle F Stagno DAlcontres 31, I-98166 Messina, Italy
推荐引用方式 GB/T 7714	Lin, YM,Sun, XY,Su, DS,et al. Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials[J]. CHEMICAL SOCIETY REVIEWS,2018,47(22):8438-8473.
APA	Lin, YM,Sun, XY,Su, DS,Centi, G,&Perathoner, S.(2018).Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials.CHEMICAL SOCIETY REVIEWS,47(22),8438-8473.
MLA	Lin, YM,et al."Catalysis by hybrid sp(2)/sp(3) nanodiamonds and their role in the design of advanced nanocarbon materials".CHEMICAL SOCIETY REVIEWS 47.22(2018):8438-8473.