Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst

doi:10.1002/chem.201804284

CORC > 高能物理研究所 > 中国科学院高能物理研究所 > 中国科学院高能物理研究所 > 中国散裂中子源

	Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst
	Huang ZW(黄志伟); Qian, Bing-Bing; Mei, Lei; Zhang, Zhi-Hui; Huang, Zhi-Wei; Hu, Kong-Qiu; Shi WQ(石伟群); Chai ZF(柴之芳); Yu JP(于吉攀); Mei L(梅雷)
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2018
卷号	24 期号:63 页码:16766-16769
关键词	actinides catalyst porphyrins selective dye adsorption uranyl-organic frameworks
ISSN号	0947-6539
DOI	10.1002/chem.201804284
文献子类	Article
英文摘要	Uranyl-organic frameworks (UOFs) have recently been the object of many research endeavors due to the unique coordination mode of uranyl ions and their attractive physicochemical properties. Here, a new (3,4)-connected UOF (U-IHEP-4) assembled from uranyl and porphyrin ligand tetrakis(4-carboxyphenyl)porphyrin (H4TCPP) is reported, which represents the first case of actinide porphyrinic MOFs. Adsorption experiments in DMF solution demonstrated that U-IHEP-4 selectively adsorbs positively charged dyes, which is in line with its negatively charged framework and large pore volume ratio (90 %). Remarkably, U-IHEP-4 exhibited high catalytic activity for the dehydrogenation of N-heterocycles to synthesize the corresponding aromatic heterocycles and it can be used as an efficient heterogeneous catalyst.
电子版国际标准刊号	1521-3765
WOS关键词	METAL-ORGANIC FRAMEWORKS ; COORDINATION POLYMERS ; CARBENE INSERTION ; HIGHLY EFFICIENT ; RATIONAL DESIGN ; N-HETEROCYCLES ; URANIUM ; TOPOLOGY ; CRYSTAL ; CONSTRUCTION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000450258500010
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/286880]
专题	中国科学院高能物理研究所_中国散裂中子源高能物理研究所_多学科研究中心
通讯作者	Shi WQ(石伟群)
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Huang ZW,Qian, Bing-Bing,Mei, Lei,et al. Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst[J]. CHEMISTRY-A EUROPEAN JOURNAL,2018,24(63):16766-16769.
APA	黄志伟.,Qian, Bing-Bing.,Mei, Lei.,Zhang, Zhi-Hui.,Huang, Zhi-Wei.,...&Yu, Ji-Pan.(2018).Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst.CHEMISTRY-A EUROPEAN JOURNAL,24(63),16766-16769.
MLA	黄志伟,et al."Actinide-Based Porphyrinic MOF as a Dehydrogenation Catalyst".CHEMISTRY-A EUROPEAN JOURNAL 24.63(2018):16766-16769.