Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance

doi:10.1039/c8qi00322j

	Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance
	Li, BX; Liu PF(刘鹏飞); Zhu, QL; Wu, XT; Wu, LM; Liu, PF; Chen, H; Lin, H
刊名	INORGANIC CHEMISTRY FRONTIERS
	2018
卷号	5 期号:6 页码:1458-1462
ISSN号	2052-1553
DOI	10.1039/c8qi00322j
文献子类	Article
英文摘要	The search for new non-centrosymmetric (NCS) crystals with wide energy-gaps (E-g) and strong second-harmonic generation (SHG) responses has become one of the greatest challenges in the mid- and far-infrared (MFIR) nonlinear optical (NLO) field. In this work, a novel quaternary NCS material Sr5ZnGa6S15 (SZGS), which contains a complex 3D anionic framework and possesses the optical properties required for the MFIR NLO applications, especially the good balance between wide E-g (3.15 eV) and large SHG response (d(ij) = 1.2 x AgGaS2), has been discovered for the first time. Moreover, the result of theoretical calculation further indicates that the 3D [ZnGa6S15](10-) framework makes definitive contributions to the NLO properties. All these studies demonstrate that SZGS is a promising NLO candidate in the MFIR region.
WOS关键词	2ND-HARMONIC GENERATION RESPONSE ; LASER-DAMAGE THRESHOLDS ; METAL CHALCOGENIDES ; SE ; SULFIDES ; GE ; CRYSTAL ; GAP ; SN ; PREDICTION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000435296200028
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/286073]
专题	高能物理研究所_东莞分部高能物理研究所_加速器中心中国科学院高能物理研究所_中国散裂中子源
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Li, BX,Liu PF,Zhu, QL,et al. Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance[J]. INORGANIC CHEMISTRY FRONTIERS,2018,5(6):1458-1462.
APA	Li, BX.,刘鹏飞.,Zhu, QL.,Wu, XT.,Wu, LM.,...&Lin, H.(2018).Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance.INORGANIC CHEMISTRY FRONTIERS,5(6),1458-1462.
MLA	Li, BX,et al."Sr5ZnGa6S15: a new quaternary non-centrosymmetric semiconductor with a 3D framework structure displaying excellent nonlinear optical performance".INORGANIC CHEMISTRY FRONTIERS 5.6(2018):1458-1462.