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	Chemical composition and size distribution of summertime pm2.5 at a high altitude remote location in the northeast of the qinghai-xizang (tibet) plateau: insights into aerosol sources and processing in free troposphere
	Xu, J. Z.1; Zhang, Q.2,3; Wang, Z. B.1; Yu, G. M.1; Ge, X. L.2; Qin, X.1
刊名	Atmospheric chemistry and physics
	2015
卷号	15期号:9页码:5069-5081
ISSN号	1680-7316
DOI	10.5194/acp-15-5069-2015
通讯作者	Xu, j. z.(jzxu@lzb.ac.cn)
英文摘要	Aerosol filter samples were collected at a high-elevation mountain observatory (4180 ma.s.l.) in the northeastern part of the qinghai-xizang (tibet) plateau (qxp) during summer 2012 using a low-volume sampler and a micro-orifice uniform deposit impactor (moudi). these samples were analyzed for water-soluble inorganic ions (wsis), organic carbon (oc), elemental carbon (ec), water-soluble organic carbon (wsoc), and total organic nitrogen (ton) to elucidate the size-resolved chemical composition of free tropospheric aerosols in the qxp region. the average mass concentration of the sum of the analyzed species in pm2.5 (particle matter) (wsis c oc c ec c ton) was 3.74 mu g sm(-3), 36% of which was sulfate, 18% oc, 17% nitrate, 10% ammonium, 6.6% calcium, 6.4% ton, 2.6% ec, 1.5% sodium, 0.9% chloride, 0.5% magnesium, and 0.3% potassium. the size distributions of sulfate and ammonium peaked in the accumulation mode (0.32-0.56 mu m), whereas the size distributions of both nitrate and calcium peaked in the range of 1.8-3.2 mu m, suggesting the formation of nitrate on mineral dust. oc, ec and ton were also predominantly found in the accumulation mode. the bulk chemical composition and the average oxidation degree of water-soluble organic matter (wsom) were assessed using a high-resolution time-of-flight aerosol mass spectrometer (hr-tof-ams). wsom was found to be highly oxidized in all pm2.5 samples with an average oxygen-to-carbon atomic ratio (o / c) of 1.16 and an organic mass-to-organic car-bon ratio (om / oc) of 2.75. the highly oxidized wsom was likely related to active cloud processing during upslope air mass transport coupled with strongly oxidizing environments caused by snow/ice photochemistry. high average ratios of oc / ec (7.6) and wsoc / oc (0.79) suggested that organic aerosols were primarily made of secondary species. secondary organic aerosol (soa) was estimated on average accounting for 80% (62-96 %) of the pm2.5, indicating that soa is an important component of free tropospheric aerosols over the northern qxp.
收录类别	SCI
WOS关键词	SOLUBLE ORGANIC-CARBON ; AQUEOUS-PHASE REACTIONS ; MASS-SPECTROMETRY ; WESTERN CHINA ; MINERAL DUST ; SEASONAL-VARIATIONS ; OPTICAL-PROPERTIES ; FINE PARTICLES ; SECONDARY ; WATER
WOS研究方向	Meteorology & Atmospheric Sciences
WOS类目	Meteorology & Atmospheric Sciences
语种	英语
出版者	COPERNICUS GESELLSCHAFT MBH
WOS记录号	WOS:000355289100006
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2554999
专题	寒区旱区环境与工程研究所
通讯作者	Xu, J. Z.
作者单位	1.Chinese Acad Sci, Cold & Arid Regions Environm & Engn Res Inst, State Key Lab Cryospher Sci, Qilian Shan Stn Glaciol & Ecol Environm, Lanzhou 730000, Peoples R China 2.Univ Calif Davis, Dept Environm Toxicol, Davis, CA 95616 USA 3.Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
推荐引用方式 GB/T 7714	Xu, J. Z.,Zhang, Q.,Wang, Z. B.,et al. Chemical composition and size distribution of summertime pm2.5 at a high altitude remote location in the northeast of the qinghai-xizang (tibet) plateau: insights into aerosol sources and processing in free troposphere[J]. Atmospheric chemistry and physics,2015,15(9):5069-5081.
APA	Xu, J. Z.,Zhang, Q.,Wang, Z. B.,Yu, G. M.,Ge, X. L.,&Qin, X..(2015).Chemical composition and size distribution of summertime pm2.5 at a high altitude remote location in the northeast of the qinghai-xizang (tibet) plateau: insights into aerosol sources and processing in free troposphere.Atmospheric chemistry and physics,15(9),5069-5081.
MLA	Xu, J. Z.,et al."Chemical composition and size distribution of summertime pm2.5 at a high altitude remote location in the northeast of the qinghai-xizang (tibet) plateau: insights into aerosol sources and processing in free troposphere".Atmospheric chemistry and physics 15.9(2015):5069-5081.

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