Corrosion Inhibition from Thiol Self-assembly Layer: A High Pressure Perspective
Ren Quanqiang1,2; Li Ainong1; Qiu Ri2,3; Xu Likun2; Li Bei1; Sun Zhiyong2
刊名JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
2018-12-01
卷号33期号:6页码:1334-1343
关键词high pressure corrosion self-assembled layer copper dodecanethiol
ISSN号1000-2413
DOI10.1007/s11595-018-1971-0
通讯作者Qiu Ri(landy-qiu@hotmail.com)
英文摘要Taking dodecanethiol as the representative, we investigated the corrosion inhibition performance of SAL in seawater under pressures from 0.1 to 9 MPa. By using scanning Kelvin probe, the dodecanethiol SAL is confirmed to build on Cu surface, and the modification of SAL has positively shifted the surface potential to realize the inertness. Electrochemical techniques, such as electrochemical impedance spectroscopy and potentiodynamic polarization were used to reveal the corrosion behavior of Cu modified by SAL under the different pressure, i e, 0.1, 3, 6, and 9 MPa. It is indicated that the longer modification time affords better corrosion resistance to Cu. Higher static pressure is easier to deteriorate the corrosion inhibition capability due to the penetration effect. A plausible mechanism is proposed to illustrate the degradation process of SAL in the high pressure seawater environment.
资助项目Foundation of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences[MCKF201605] ; National Natural Science Foundation of China[21301161]
WOS研究方向Materials Science
语种英语
出版者JOURNAL WUHAN UNIV TECHNOLOGY
WOS记录号WOS:000457141200006
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/160819]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Qiu Ri
作者单位1.Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
2.Luoyang Ship Mat Res Inst, State Key Lab Marine Corros & Protect, Qingdao 266101, Peoples R China
3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
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Ren Quanqiang,Li Ainong,Qiu Ri,et al. Corrosion Inhibition from Thiol Self-assembly Layer: A High Pressure Perspective[J]. JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION,2018,33(6):1334-1343.
APA Ren Quanqiang,Li Ainong,Qiu Ri,Xu Likun,Li Bei,&Sun Zhiyong.(2018).Corrosion Inhibition from Thiol Self-assembly Layer: A High Pressure Perspective.JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION,33(6),1334-1343.
MLA Ren Quanqiang,et al."Corrosion Inhibition from Thiol Self-assembly Layer: A High Pressure Perspective".JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION 33.6(2018):1334-1343.
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