Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs

doi:10.1002/ejic.201601369

	Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs
	Chai ZF(柴之芳); Zhao R(赵然); Mei L(梅雷); Hu KQ(胡孔球); Wang L(王琳); Shi WQ(石伟群); Zhao, R; Mei, L; Hu, KQ; Shi, WQ
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2017
卷号	2017 期号:11 页码:1472-1477
关键词	Heterometallic complexes Carboxylate ligands Helical structures Actinides Silver
ISSN号	1434-1948
DOI	10.1002/ejic.201601369
文献子类	Article
英文摘要	Under hydrothermal conditions, two new 3D actinide- silver (An-Ag) heterometallic coordination polymers, namely, [Ag(UO2)(2)(mu(2)-OH)(bpdc)(2)(H2O)(2)](n) (1) and [Ag3Th6(mu(3)-O)(mu(3)-OH)(mu(2)-OH)(6)(bpdc)(6)(NO3)(6)center dot H2O](n) (2, H(2)bpdc = 2,2'-bipyridine- 3,3'-dicarboxylic acid), were assembled through a hardsoft recognition strategy. Compounds 1 and 2 were character-ized by single-crystal X-ray diffraction, powder X-ray diffraction, and infrared spectroscopy. Both compounds are constructed through the bridging of infinite polynuclear An-bpdc chiral helical chains by AgI cations. Compound 2 represents the first ThIVAgI heterometallic coordination polymer. Furthermore, the thermal stability and luminescence properties of 1 were studied.
电子版国际标准刊号	1099-0682
WOS关键词	METAL-ORGANIC FRAMEWORKS ; URANYL-ION COMPLEXES ; CRYSTAL-STRUCTURE ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; POSTSYNTHETIC REARRANGEMENT/METALATION ; BIMETALLIC URANYL ; LIGAND SYNTHESIS ; HYBRID MATERIALS ; 2,2'-BIPYRIDYL-3,3'-DICARBOXYLATE
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000397852200007
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/285386]
专题	高能物理研究所_多学科研究中心中国科学院高能物理研究所_中国散裂中子源
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Chai ZF,Zhao R,Mei L,et al. Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017,2017(11):1472-1477.
APA	柴之芳.,赵然.,梅雷.,胡孔球.,王琳.,...&Wang, L.(2017).Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017(11),1472-1477.
MLA	柴之芳,et al."Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2017.11(2017):1472-1477.