Control of Spatially Homogeneous Distribution of Heteroatoms to Produce Red TiO2 Photocatalyst for Visible-Light Photocatalytic Water Splitting

doi:10.1002/chem.201805283

	Control of Spatially Homogeneous Distribution of Heteroatoms to Produce Red TiO2 Photocatalyst for Visible-Light Photocatalytic Water Splitting
	Cheng, Hui-Ming 1,7; Liu, Gang 6,7; Wang, Lianzhou 2,3; Irvine, John T. S.4; Yang, Yongqiang 7; Feng, Ningdong 5; Zhu, Huaze 7; Tan, Jun 7; Hong, Xingxing 6,7
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2019-02-01
卷号	25 期号:7 页码:1787-1794
关键词	doping photocatalysis photochemistry titanium water splitting
ISSN号	0947-6539
DOI	10.1002/chem.201805283
英文摘要	The strong band-to-band absorption of photocatalysts spanning the whole visible-light region (400-700 nm) is critically important for solar-driven photocatalysis. Although it has been actively and widely used as a photocatalyst for various reactions in the past four decades, TiO2 has a very poor ability to capture the whole spectrum of visible light. In this work, by controlling the spatially homogeneous distribution of boron and nitrogen heteroatoms in anatase TiO2 microspheres with a predominance of high-energy {001} facets, a strong visible-light absorption spectrum with a sharp edge beyond 680 nm has been achieved. The red TiO2 obtained with homogeneous doping of boron and nitrogen shows no increase in defects like Ti3+ that are commonly observed in doped TiO2. More importantly, it has the ability to induce photocatalytic water oxidation to produce oxygen under the irradiation of visible light beyond 550 nm and also the photocatalytic reduction of water to produce hydrogen under visible light. These results demonstrate the great promise of using red TiO2 for visible-light photocatalytic water splitting and also reveal an attractive strategy for realizing the wide-spectrum visible-light absorption of wide-band-gap oxide photocatalysts.
资助项目	National Natural Science Foundation of China[51825204] ; National Natural Science Foundation of China[51572266] ; National Natural Science Foundation of China[21633009] ; National Natural Science Foundation of China[51629201] ; Major Basic Research Program ; Ministry of Science and Technology of China[2014CB239401] ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences[QYZDB-SSW-JSC039] ; Newton Advanced Fellowship
WOS关键词	HYDROGEN-PRODUCTION ; NITROGEN ; COCATALYSTS ; ABSORPTION ; REACTIVITY ; NANOSHEETS ; OXIDATION ; REDUCTION ; CRYSTALS ; OXIDES
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000459811300026
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Basic Research Program ; Major Basic Research Program ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Newton Advanced Fellowship ; Newton Advanced Fellowship ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Basic Research Program ; Major Basic Research Program ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Newton Advanced Fellowship ; Newton Advanced Fellowship ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Basic Research Program ; Major Basic Research Program ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Newton Advanced Fellowship ; Newton Advanced Fellowship ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Major Basic Research Program ; Major Basic Research Program ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Key Research Program of Frontier Sciences, Chinese Academy of Sciences ; Newton Advanced Fellowship ; Newton Advanced Fellowship
内容类型	期刊论文
源URL	[http://ir.wipm.ac.cn/handle/112942/14191]
专题	中国科学院武汉物理与数学研究所
通讯作者	Liu, Gang
作者单位	1.Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, 1001 Xueyuan Rd, Shenzhen 518055, Peoples R China 2.Univ Queensland, AIBN, St Lucia, Qld 4072, Australia 3.Univ Queensland, Sch Chem Engn, Nanomat Ctr, St Lucia, Qld 4072, Australia 4.Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland 5.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom Mol Phys, Key Lab Magnet Resonance Biol Syst, Wuhan Ctr Magnet Resonance,Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China 6.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China 7.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Cheng, Hui-Ming,Liu, Gang,Wang, Lianzhou,et al. Control of Spatially Homogeneous Distribution of Heteroatoms to Produce Red TiO2 Photocatalyst for Visible-Light Photocatalytic Water Splitting[J]. CHEMISTRY-A EUROPEAN JOURNAL,2019,25(7):1787-1794.
APA	Cheng, Hui-Ming.,Liu, Gang.,Wang, Lianzhou.,Irvine, John T. S..,Yang, Yongqiang.,...&Hong, Xingxing.(2019).Control of Spatially Homogeneous Distribution of Heteroatoms to Produce Red TiO2 Photocatalyst for Visible-Light Photocatalytic Water Splitting.CHEMISTRY-A EUROPEAN JOURNAL,25(7),1787-1794.
MLA	Cheng, Hui-Ming,et al."Control of Spatially Homogeneous Distribution of Heteroatoms to Produce Red TiO2 Photocatalyst for Visible-Light Photocatalytic Water Splitting".CHEMISTRY-A EUROPEAN JOURNAL 25.7(2019):1787-1794.