Ordered arrays of semi-crown ligands on an Au(111) electrode surface: in situ STM study | |
Pan, GB; Li, HJ; Yuan, QH; Chen, YJ; Wan, LJ; Bai, CL | |
刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY |
2004-08-01 | |
卷号 | 47期号:4页码:320-325 |
关键词 | Au(111) Cyclic Voltammetry Ordered Array In Situ Stm |
ISSN号 | 1006-9291 |
DOI | 10.1360/04yb0019 |
英文摘要 | In situ scanning tunneling microscopy (STM) and cyclic voltammetry were employed to investigate the adsorption structures of three semi-crown ligands on an Au(111) surface under the potential control. It is found that all the molecules formed ordered arrays in 0.1 mol/L HCIO4 solution, although their geometric structures are complex and asymmetric. The driving force was supposed to come from the balance between intermolecular and molecule-substrate interactions. High resolution STM images revealed internal molecular structures, orientations and packing arrangements in the ordered adlayers. The results are useful for preparing ordered arrays of transition metal-mediated nanostructures. |
语种 | 英语 |
出版者 | SCIENCE CHINA PRESS |
WOS记录号 | WOS:000224391900008 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/81853] |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, YJ |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Pan, GB,Li, HJ,Yuan, QH,et al. Ordered arrays of semi-crown ligands on an Au(111) electrode surface: in situ STM study[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2004,47(4):320-325. |
APA | Pan, GB,Li, HJ,Yuan, QH,Chen, YJ,Wan, LJ,&Bai, CL.(2004).Ordered arrays of semi-crown ligands on an Au(111) electrode surface: in situ STM study.SCIENCE IN CHINA SERIES B-CHEMISTRY,47(4),320-325. |
MLA | Pan, GB,et al."Ordered arrays of semi-crown ligands on an Au(111) electrode surface: in situ STM study".SCIENCE IN CHINA SERIES B-CHEMISTRY 47.4(2004):320-325. |
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