A comparative study of cation and anion cluster reaction products: The reaction mechanisms of lead clusters with benzene in gas phase | |
Xing, XP; Tian, ZX; Liu, HT; Tang, ZC | |
刊名 | JOURNAL OF PHYSICAL CHEMISTRY A |
2003-10-16 | |
卷号 | 107期号:41页码:8484-8491 |
ISSN号 | 1089-5639 |
DOI | 10.1021/mrdlab.icas.ac.cn |
英文摘要 | The cation and anion products of the reactions between lead clusters produced in the laser ablation and the benzene molecules seeded in argon were studied by high-resolution reflectron time-of-flight mass spectrometer (RTOFMS). The dominant cation products were Pb/benzene association complexes, while the dominant anion products were dehydrogenated species, [PbmCn](-), [PbmCnHk](-), etc. One important intermediate distinguished in the anion reactions was [Pb-m(C6H5)](-) product. Two conspicuously different and independent reaction mechanisms were proposed for lead cluster cations and anions, respectively. |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000185857400015 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/81177] |
专题 | 中国科学院化学研究所 |
通讯作者 | Tang, ZC |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Xing, XP,Tian, ZX,Liu, HT,et al. A comparative study of cation and anion cluster reaction products: The reaction mechanisms of lead clusters with benzene in gas phase[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2003,107(41):8484-8491. |
APA | Xing, XP,Tian, ZX,Liu, HT,&Tang, ZC.(2003).A comparative study of cation and anion cluster reaction products: The reaction mechanisms of lead clusters with benzene in gas phase.JOURNAL OF PHYSICAL CHEMISTRY A,107(41),8484-8491. |
MLA | Xing, XP,et al."A comparative study of cation and anion cluster reaction products: The reaction mechanisms of lead clusters with benzene in gas phase".JOURNAL OF PHYSICAL CHEMISTRY A 107.41(2003):8484-8491. |
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