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Preparations of pure ISeCN, ISCN, and INCO
Li, YM; Qiao, ZM; Sun, Q; Zhao, JC; Li, HY; Wang, DX
刊名INORGANIC CHEMISTRY
2003-12-15
卷号42期号:25页码:8446-8448
ISSN号0020-1669
DOI10.1021/ic030158v
英文摘要Pure INCO, ISCN, and the hitherto unknown molecule ISeCN have been prepared in the Hel photoelectron spectrometer (PES) by the heterogeneous reactions of ICI gas with AgNCO, AgSCN at room temperature, and AgSeCN at -9 (+/-1) degreesC, respectively. They were characterized on line by PES experiments and OVGF calculations. The well-matched results between the PES experiments and OVGF calculations not only show that the new reaction is a good reaction to prepare pure INCO and pure ISCN, but also that the new compound prepared by passing the ICI gas over the freshly AgSeCN powder at -9(+/-1) degreesC is the hitherto unknown ISeCN.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000187162900040
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/81041]  
专题中国科学院化学研究所
通讯作者Li, HY
作者单位1.Acad Sinica, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Li, YM,Qiao, ZM,Sun, Q,et al. Preparations of pure ISeCN, ISCN, and INCO[J]. INORGANIC CHEMISTRY,2003,42(25):8446-8448.
APA Li, YM,Qiao, ZM,Sun, Q,Zhao, JC,Li, HY,&Wang, DX.(2003).Preparations of pure ISeCN, ISCN, and INCO.INORGANIC CHEMISTRY,42(25),8446-8448.
MLA Li, YM,et al."Preparations of pure ISeCN, ISCN, and INCO".INORGANIC CHEMISTRY 42.25(2003):8446-8448.
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