Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization

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	Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization
	Xu, YA; Xue, H; Zhang, SB; Gao, LX; Ding, MX
刊名	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
	2003-04-01
卷号	24 期号:4 页码:748-750
关键词	Optically Active Polymer Menthyl Methacrylate Anionic Polymerization Group Transfer Polymerization Radical Polymerization
ISSN号	0251-0790
英文摘要	The optically active polymers of ( -) -menthyl methacrylate were obtained by anionic, group transfer polymerization (GTP) and radical polymerization methods. The influences of different polymerization methods on specific rotation, yield and stereoregularity of polymers were studied. In the fluorene lithium and, (S, S)-(+)-2, 3-dimethoxy-1, 4-bis (dimethylamino) butane [(+)-DDB] complex initiative system, the specific rotation values rise slightly with the increase of molecular weight. There is no obvious difference in the specific rotation values of PMnMAs obtained by different, polymerization methods, but there is an obvious variation in stereoregularity of the polymers. And the change of the optical activity of PMn-MA is slight as compared with the variation of the stereoregularity. The tacticity of polymers is mainly syndiotactic.
语种	英语
出版者	HIGHER EDUCATION PRESS
WOS记录号	WOS:000182512000047
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/80223]
专题	中国科学院化学研究所
通讯作者	Ding, MX
作者单位	Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Xu, YA,Xue, H,Zhang, SB,et al. Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2003,24(4):748-750.
APA	Xu, YA,Xue, H,Zhang, SB,Gao, LX,&Ding, MX.(2003).Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,24(4),748-750.
MLA	Xu, YA,et al."Studies on optically active poly(menthyl methacrylate) by anionic, GTP and radical polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 24.4(2003):748-750.