Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone

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	Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone
	Huang, K; Xue, L; Hu, YC; Huang, MY; Jiang, YY
刊名	REACTIVE & FUNCTIONAL POLYMERS
	2002
卷号	50 期号:3 页码:199-203
关键词	(r)-(-)-4-methyl-2-pentanol Asymmetric Hydrogenation Silica-supported Starch Polysulfosiloxane-platinum Complex
ISSN号	1381-5148
英文摘要	A new chiral natural bio-polymer-metal complexes. silica-supported starch-polysulfosiloxane-platinum complex (SiO2-ST-Si-S-Pt) has been prepared by a very simple method, and Pt complex has been found to be able to catalyze the asymmetric hydrogenation of 4-methyl-2-pentanone to give (R)-(-)-4-methyl-2-pentanol at room temperature and under an atmospheric hydrogen pressure. The product and optical yields of 4-methyl-2-pentanol a-mounted to 73.2 and 94.1%. respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000174397400001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/78579]
专题	中国科学院化学研究所
通讯作者	Huang, K
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Huang, K,Xue, L,Hu, YC,et al. Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone[J]. REACTIVE & FUNCTIONAL POLYMERS,2002,50(3):199-203.
APA	Huang, K,Xue, L,Hu, YC,Huang, MY,&Jiang, YY.(2002).Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone.REACTIVE & FUNCTIONAL POLYMERS,50(3),199-203.
MLA	Huang, K,et al."Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone".REACTIVE & FUNCTIONAL POLYMERS 50.3(2002):199-203.