Effect of liquid crystalline ordering on the crystallization rate of a thermotropic aromatic polyester

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	Effect of liquid crystalline ordering on the crystallization rate of a thermotropic aromatic polyester
	Chen, SX; Zhai, HC; Jin, YZ
刊名	ACTA POLYMERICA SINICA
	1999-06-01
期号	3 页码:320-325
关键词	Polymeric Liquid Crystal Domain Crystallization Rate
ISSN号	1000-3304
英文摘要	The liquid crystalline (LC) ordering of nematic mesophase was investigated by measuring the transmitted depolarization light intensity of samples varied with the temperature. The depolarization intensity of a light beam passing through the sample between crossed polarisers increased with temperature during heating, and then it was decreased when the temperature clossed to Ti. The increasing of the depolarization intensity means the growth of LC ordering or domains. This result indicates that the LC ordering is different within temperature range of nematic mesophase. So that the crystallization behavior of samples crystallized from the mesophase melt of different temperatures will be different. The isothermal crystallization from mesophase melt of different LC ordering was determined by DSC. The samples were first melted at different temperature corresponding to different LC ordering for 30 min, and then crystallization was carried out at same temperature to compare their rates. The results obtained indicate that the crystallization rates from mesophase melt of different temperature were quite different for this thermotrpic aromatic polyester. It can be seen from compareison of the data between the depolization light intensity and the crystallization rate that the crystallization rate increases with increasing LC ordering or domain size at first, and then as the LC ordering was decreased the crystallization rate becomes slower when the temperature of mesophase melt close to Ti. These observations could be interpreted that high LC ordering, or large domain size, made it easy to crystallize.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000080941200011
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/75443]
专题	中国科学院化学研究所
通讯作者	Chen, SX
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Chen, SX,Zhai, HC,Jin, YZ. Effect of liquid crystalline ordering on the crystallization rate of a thermotropic aromatic polyester[J]. ACTA POLYMERICA SINICA,1999(3):320-325.
APA	Chen, SX,Zhai, HC,&Jin, YZ.(1999).Effect of liquid crystalline ordering on the crystallization rate of a thermotropic aromatic polyester.ACTA POLYMERICA SINICA(3),320-325.
MLA	Chen, SX,et al."Effect of liquid crystalline ordering on the crystallization rate of a thermotropic aromatic polyester".ACTA POLYMERICA SINICA .3(1999):320-325.