Methanol synthesis from syngas in the homogeneous system

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	Methanol synthesis from syngas in the homogeneous system
	Li, KL; Jiang, DZ
刊名	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
	1999-11-17
卷号	147 期号:1-2 页码:125-130
关键词	Methanol Homogeneous Synthesis Nickel Catalyst Low Temperature Additives
ISSN号	1381-1169
英文摘要	Homogeneous synthesis of methanol from synthetic gas was carried out in the Ni(CO)(4)/KOMe catalytic system. The influence of various factors, such as the reaction temperature, the concentration of potassium methoxide, the concentration of nickel tetracarbonyl and the reaction pressure on the catalytic activity, was discussed, respectively, and the most preferred conditions were obtained. The results showed that methanol could be prepared from carbon monoxide and hydrogen under mild reaction conditions. The catalytic reactions were operated most preferably at 378 K and 1.8 MPa. The activity of catalyst characterized by space-time yield (STY) is about 4 mol/1 h. The effect of additives containing N-, O-, S-elements on the catalytic activity was also investigated. (C) 1999 Elsevier Science B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000083978400018
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/75323]
专题	中国科学院化学研究所
通讯作者	Jiang, DZ
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Li, KL,Jiang, DZ. Methanol synthesis from syngas in the homogeneous system[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):125-130.
APA	Li, KL,&Jiang, DZ.(1999).Methanol synthesis from syngas in the homogeneous system.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),125-130.
MLA	Li, KL,et al."Methanol synthesis from syngas in the homogeneous system".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):125-130.