Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride

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	Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride
	Gong, JF; Fan, QH; Jiang, DZ
刊名	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
	1999-11-17
卷号	147 期号:1-2 页码:113-124
关键词	Nickel Catalyst Carbonylation Acetic Anhydride Ligand Mechanism
ISSN号	1381-1169
英文摘要	Liquid phase carbonylation of methyl acetate to acetic anhydride using nickel catalyst with methyl iodide promoter is reported. Effect of different catalyst precursors, total reaction pressure, hydrogen partial pressure, temperature, catalyst, lithium acetate and methyl iodide concentration, a variety of ligands on the activity and selectivity of nickel catalyst has been investigated. Additionally, FT-IR spectra of the reaction solution were studied and possible side reactions in the carbonylation were examined. Based on these observations, a proposed mechanism for the homogeneous nickel-catalyzed carbonylation of methyl acetate was discussed. (C) 1999 Elsevier Science B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000083978400017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/74847]
专题	中国科学院化学研究所
通讯作者	Jiang, DZ
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Gong, JF,Fan, QH,Jiang, DZ. Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):113-124.
APA	Gong, JF,Fan, QH,&Jiang, DZ.(1999).Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),113-124.
MLA	Gong, JF,et al."Nickel-catalyzed carbonylation of methyl acetate to acetic anhydride".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):113-124.