Synthesis and characteristics of poly(arylene ether diketone)s | |
Gao, XS; Lu, FC | |
刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
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1998 | |
卷号 | 16期号:4页码:316-326 |
关键词 | Poly(Arylene Ether Diketone) Thermal Behavior High-temperature Polymers Permeability |
ISSN号 | 0256-7679 |
英文摘要 | Poly(arylene ether diketone)s were prepared by the aromatic nucleophilic displacement reaction of 4,4'-difluorobenzil with different bisphenols in the presence of anhydrous potassium carbonate in diphenylsulfone at elevated temperature. The polymers obtained had inherent viscosity of 0.51 similar to 0.63 dL/g, and exhibited glass transition temperature ranging from 136 similar to 217 degrees C mainly depending on the bisphenols used in the polymer synthesis. Thermogravimetry of these polymers showed excellent thermal stability, indicating that 10% weight losses of the polymers were observed in the range above 428 degrees C and 438 degrees C in air and nitrogen, respectively. The mechanical properties of these polymers were also described and the permeability of five polymers for H-2, O-2 and N-2 was determined at 30 degrees C. |
语种 | 英语 |
出版者 | SCIENCE PRESS |
WOS记录号 | WOS:000077093400006 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/74271] ![]() |
专题 | 中国科学院化学研究所 |
作者单位 | 1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, China Petrochem Corp, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, XS,Lu, FC. Synthesis and characteristics of poly(arylene ether diketone)s[J]. CHINESE JOURNAL OF POLYMER SCIENCE,1998,16(4):316-326. |
APA | Gao, XS,&Lu, FC.(1998).Synthesis and characteristics of poly(arylene ether diketone)s.CHINESE JOURNAL OF POLYMER SCIENCE,16(4),316-326. |
MLA | Gao, XS,et al."Synthesis and characteristics of poly(arylene ether diketone)s".CHINESE JOURNAL OF POLYMER SCIENCE 16.4(1998):316-326. |
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