Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes | |
Cao, Chang-Yan1,2; Guo, Wei1; Cui, Zhi-Min3; Song, Wei-Guo1; Cai, Wei2 | |
刊名 | JOURNAL OF MATERIALS CHEMISTRY |
2011 | |
卷号 | 21期号:9页码:3204-3209 |
ISSN号 | 0959-9428 |
DOI | 10.1039/c0jm03749d |
英文摘要 | A rapid method based on an efficient gas/liquid interfacial microwave-assisted process has been developed to synthesize flowerlike NiO hollow nanosphere precursors, which were then transformed to NiO by simple calcinations. The wall of the sphere is composed of twisted NiO nanosheets that intercalated with each other. Such hollow structure is different from widely reported flowerlike nanostructures with solid cores. An Ostwald ripening mechanism was proposed for the formation of the hollow nanostructures. The products were characterized by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, high-resolution TEM, energy-dispersive X-ray analysis, and N(2) adsorption-desorption methods. These flowerlike NiO hollow nanospheres have high surface area of 176 m(2) g(-1). Electrochemical properties show a high specific capacitance of 585 F g(-1) at a discharge current of 5 A g(-1) and excellent cycling stability, suggesting its promising potentials in supercapacitors. |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000287369300059 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/72745] |
专题 | 中国科学院化学研究所 |
通讯作者 | Song, Wei-Guo |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Harbin Inst Technol, Sch Mat Sci & Engn, Harbin 150001, Peoples R China 3.Beijing Univ Aeronaut & Astronaut, Sch Chem & Environm Engn, Beijing 100191, Peoples R China |
推荐引用方式 GB/T 7714 | Cao, Chang-Yan,Guo, Wei,Cui, Zhi-Min,et al. Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes[J]. JOURNAL OF MATERIALS CHEMISTRY,2011,21(9):3204-3209. |
APA | Cao, Chang-Yan,Guo, Wei,Cui, Zhi-Min,Song, Wei-Guo,&Cai, Wei.(2011).Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes.JOURNAL OF MATERIALS CHEMISTRY,21(9),3204-3209. |
MLA | Cao, Chang-Yan,et al."Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes".JOURNAL OF MATERIALS CHEMISTRY 21.9(2011):3204-3209. |
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