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Performance improvement of annealing-free P3HT: PCBM-based polymer solar cells via 3-methylthiophene additive
Peng, Bo2; Guo, Xia; Zou, Yingping2; Pan, Chunyue2; Li, Yongfang1
刊名JOURNAL OF PHYSICS D-APPLIED PHYSICS
2011-09-14
卷号44期号:36
ISSN号0022-3727
DOI10.1088/0022-3727/44/36/365101
英文摘要In this work, we studied the effect of 3-methylthiophene (3MT) and 3-hexylthiophene (3HT) additives on the morphology and photovoltaic performance of the polymer solar cells (PSCs) based on P3HT : PCBM (1 : 1 w/w). The P3HT : PCBM blend films prepared from the solutions with 3MT or 3HT additive show enhanced absorption in the 500-650 nm wavelength range and higher hole mobility than that of the film without the additives. X-ray diffraction data indicate a smaller interlayer distance of the conjugated backbones in the w3MT- or 3HT-processed films. Atomic force microscopy images of the 3MT-processed films demonstrate a nanoscaled phase separation and interpenetrating network morphology between the donor and the accept phases. The power conversion efficiency of PSCs based on 3MT-processed blend films without thermal annealing reached 3.72% which is increased by 30% over that of the devices without the additive.
语种英语
出版者IOP PUBLISHING LTD
WOS记录号WOS:000294770600004
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/72431]  
专题中国科学院化学研究所
通讯作者Li, Yongfang
作者单位1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
推荐引用方式
GB/T 7714
Peng, Bo,Guo, Xia,Zou, Yingping,et al. Performance improvement of annealing-free P3HT: PCBM-based polymer solar cells via 3-methylthiophene additive[J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS,2011,44(36).
APA Peng, Bo,Guo, Xia,Zou, Yingping,Pan, Chunyue,&Li, Yongfang.(2011).Performance improvement of annealing-free P3HT: PCBM-based polymer solar cells via 3-methylthiophene additive.JOURNAL OF PHYSICS D-APPLIED PHYSICS,44(36).
MLA Peng, Bo,et al."Performance improvement of annealing-free P3HT: PCBM-based polymer solar cells via 3-methylthiophene additive".JOURNAL OF PHYSICS D-APPLIED PHYSICS 44.36(2011).
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