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Gamma Radiation on Poly(epsilon-caprolactone) in the Presence of Vinyltrimethoxysilane
Wang, Shusheng1,2,3; Han, Changyu1; Han, Lijing1; Wang, Xuemei1; Bian, Junjia1; Zhuang, Yugang1; Dong, Lisong1
刊名POLYMER ENGINEERING AND SCIENCE
2011-02-01
卷号51期号:2页码:369-376
ISSN号0032-3888
DOI10.1002/pen.21832
英文摘要The performance and radiation-induced cross-linking of polycaprolactone (PCL) in the presence of vinyltrimethoxysilane (VTMS) have been investigated. Radiation-induced cross-linking of PCL in the presence of VTMS followed the Charlesby-Pinner equation, and VTMS promoted the radiation-induced cross-linking of PCL. As the concentration of VTMS increased, the gelation dose and the ratio of degradation to cross-linking (p(0)/q(0)) decreased and the efficiency of radiation-induced cross-linking increased. Differential scanning calorimetry analyses showed differences between the first and second scans. Glass-transition temperature (T(g)) and mechanical properties of the polymers increased. Radiation-induced cross-linking of PCL in the presence of VTMS was found to retard hydrolytic degradation greatly. POLYM. ENG. SCI., 51:369-376, 2011. (C) 2010 Society of Plastics Engineers
语种英语
出版者JOHN WILEY & SONS INC
WOS记录号WOS:000286561100021
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/72169]  
专题中国科学院化学研究所
通讯作者Han, Changyu
作者单位1.Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun, Peoples R China
2.Jilin Agr Univ, Coll Biol Life, Changchun, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Wang, Shusheng,Han, Changyu,Han, Lijing,et al. Gamma Radiation on Poly(epsilon-caprolactone) in the Presence of Vinyltrimethoxysilane[J]. POLYMER ENGINEERING AND SCIENCE,2011,51(2):369-376.
APA Wang, Shusheng.,Han, Changyu.,Han, Lijing.,Wang, Xuemei.,Bian, Junjia.,...&Dong, Lisong.(2011).Gamma Radiation on Poly(epsilon-caprolactone) in the Presence of Vinyltrimethoxysilane.POLYMER ENGINEERING AND SCIENCE,51(2),369-376.
MLA Wang, Shusheng,et al."Gamma Radiation on Poly(epsilon-caprolactone) in the Presence of Vinyltrimethoxysilane".POLYMER ENGINEERING AND SCIENCE 51.2(2011):369-376.
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