Catalytic Organic Reactions in CO2/H2O Medium

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	Catalytic Organic Reactions in CO2/H2O Medium
	Wu Suxiang; Fan Honglei; Cheng Yan; Wang Qian; Han Buxing
刊名	PROGRESS IN CHEMISTRY
	2010-07-01
卷号	22 期号:7 页码:1286-1294
关键词	Green Chemistry Mixed Green Solvents Co2 H2o Catalysis Organic Reaction
ISSN号	1005-281X
英文摘要	Green chemistry is the trend of chemistry in the future. Utilization of green solvents effectively is one of the, important topics in green chemistry. CO2/H2O system is green reaction medium with some unique features, and can be used in different chemical reactions. Especially, it can be used in the reactions catalyzed by weak acids, in which the use of conventional hazardous acids can be avoided. In this review, we first discuss the variation of the acidity of CO2/H2O system with temperature and pressure, then some chemical reactions in CO2/H2O system are discussed, including dehydration reaction, alkylation reaction, citronellal cyclization reaction, diazonium reaction, conversion of polyalcohol to cyclic ether, oxybromination reaction, selective reduction of nitroarenes, polysaccharide hydrolysis, conversion of biomass, hydrolysis of propylene oxide, decarboxylation reaction, oxidation of alcohols, enantioselective sulfoxidation, asymmetric reduction of ketones. Finally, the future directions for the applications of CO2/H2O system in chemical reactions are discussed briefly.
语种	英语
出版者	CHINESE ACAD SCIENCES
WOS记录号	WOS:000280274000005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/70597]
专题	中国科学院化学研究所
通讯作者	Han Buxing
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wu Suxiang,Fan Honglei,Cheng Yan,et al. Catalytic Organic Reactions in CO2/H2O Medium[J]. PROGRESS IN CHEMISTRY,2010,22(7):1286-1294.
APA	Wu Suxiang,Fan Honglei,Cheng Yan,Wang Qian,&Han Buxing.(2010).Catalytic Organic Reactions in CO2/H2O Medium.PROGRESS IN CHEMISTRY,22(7),1286-1294.
MLA	Wu Suxiang,et al."Catalytic Organic Reactions in CO2/H2O Medium".PROGRESS IN CHEMISTRY 22.7(2010):1286-1294.