Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties

doi:10.1007/s10904-010-9333-1

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	Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties
	Wang, Zhuo 1; Bai, Feng-Ying 1; Xing, Yong-Heng 1; Xie, Yan 1; Zeng, Xiao-Qing 2; Ge, Mao-Fa 2; Niu, Shu-Yun 1
刊名	JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
	2010-06-01
卷号	20 期号:2 页码:242-249
关键词	Lanthanide Complexes Glutaric Acid Crystal Structures Thermal Stability 2 5-pyridine Dicarboxylic Acid
ISSN号	1574-1443
DOI	10.1007/s10904-010-9333-1
英文摘要	A series of new lanthanide coordination polymers, Ln(pydc)(Hglu) (Ln = Nd(1), Pr(2); H(2)glu = glutaric acid; 2,5-H(2)pydc = 2,5-pyridine dicarboxylic acid), have been synthesized hydrothermally from the self-assembly of the lanthanide ions (Ln(3+))with rigid 2,5-pyridine dicarboxylic acid and flexible glutaric acid. They were characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Structural analyses reveal that both of the complexes were crystallized in monoclinic space group P2(1)/c and have intricate 3D net-structures, which contain an infinite 1D Ln-O-Ln chain structure. In addition, the phase purities of the bulk samples were identified by X-ray powder diffraction. The thermogravimetric analysis of 1 is discussed in detail.
语种	英语
出版者	SPRINGER
WOS记录号	WOS:000277284600006
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/69977]
专题	中国科学院化学研究所
通讯作者	Xing, Yong-Heng
作者单位	1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Wang, Zhuo,Bai, Feng-Ying,Xing, Yong-Heng,et al. Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties[J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,2010,20(2):242-249.
APA	Wang, Zhuo.,Bai, Feng-Ying.,Xing, Yong-Heng.,Xie, Yan.,Zeng, Xiao-Qing.,...&Niu, Shu-Yun.(2010).Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties.JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS,20(2),242-249.
MLA	Wang, Zhuo,et al."Rigid and Flexible Lanthanide Complexes with an Infinite Ln-O-Ln Framework: Synthesis, Structure and Properties".JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS 20.2(2010):242-249.