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	Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water
	Wu, Suxiang; Fan, Honglei; Xie, Ye; Cheng, Yan; Wang, Qian; Zhang, Zhaofu; Han, Buxing
刊名	GREEN CHEMISTRY
	2010
卷号	12期号:7页码:1215-1219
ISSN号	1463-9262
DOI	10.1039/c002553d
英文摘要	The CO2-water system has the potential to serve as a substitute for mineral acids for some reactions in acidic media. In this work, two reactions under hydrothermal conditions with and without CO2 were studied-the conversion of inulin to 5-hydroxymethylfurfural (5-HMF), and the hydrolysis of propylene oxide to 1,2-propanediol (1,2-PDO). The effects of CO2 pressure, reaction temperature and reactant concentration on the yield of 5-HMF and 1,2-PDO were examined. It was demonstrated that CO2 could increase the yields of 5-HMF and 1,2-PDO considerably under optimized conditions. The methods to prepare 5-HMF and 1,2-PDO are greener, in that conventional acids are not required and the solution is neutralized automatically after depressurization.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000279566300014
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/69133]
专题	中国科学院化学研究所
通讯作者	Wu, Suxiang
作者单位	Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wu, Suxiang,Fan, Honglei,Xie, Ye,et al. Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water[J]. GREEN CHEMISTRY,2010,12(7):1215-1219.
APA	Wu, Suxiang.,Fan, Honglei.,Xie, Ye.,Cheng, Yan.,Wang, Qian.,...&Han, Buxing.(2010).Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water.GREEN CHEMISTRY,12(7),1215-1219.
MLA	Wu, Suxiang,et al."Effect of CO2 on conversion of inulin to 5-hydroxymethylfurfural and propylene oxide to 1,2-propanediol in water".GREEN CHEMISTRY 12.7(2010):1215-1219.

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