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Electroluminescent Block Copolymers Containing Oxadiazole and Thiophene via ATRP
Yang, Qian; Jin, Hao; Xu, Yiding; Shen, Zhihao; Fan, Xinghe; Zou, Dechun; Zhou, Qifeng
刊名JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
2010-12-15
卷号48期号:24页码:5670-5678
关键词Atom Transfer Radical Polymerization (Atrp) Block Copolymer Electroluminescence Light Emitting Diodes (Leds) Liquid Crystalline Polymers (Lcp) Living Radical Polymerization (Lap) Luminescence Oxadiazole Thiophene
ISSN号0887-624X
DOI10.1002/pola.24348
英文摘要Block copolymers containing thiophene units in one block and oxadiazole (OXD) units in the other were prepared Atom transfer radical polymerization method was used to obtain the thiophene containing mesogen jacketed polymers and the kinetic study indicated that the polymerization was controllable and the polymers could be used to initiate the polymerization of the OXD containing monomers Photo luminescent spectra indicated that the fluorescence quantum yields of the polymers increased with increasing content of OXD And more OXD domains that is more interfaces between the hole trans port parts and electron transport parts resulting in the higher probability of exciplex formation The electroluminescent devices containing the block copolymer with 64 mol % OXD as theemissive layer had a maximum brightness of 127 cd/m(2) and an extremely low onset voltage of 7 7 V which indicated that the injection and transport of charge carriers were facilitated and the number of charge carriers was sufficiently high in early time after the voltage was turned on (c) 2010 Wiley Periodicals Inc J Polym Sci Part A Polym Chem 48 5670-5678 2010
语种英语
出版者JOHN WILEY & SONS INC
WOS记录号WOS:000285485700004
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/68837]  
专题中国科学院化学研究所
通讯作者Fan, Xinghe
作者单位Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Key Lab Polymer Chem & Phys,Minist Educ, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Yang, Qian,Jin, Hao,Xu, Yiding,et al. Electroluminescent Block Copolymers Containing Oxadiazole and Thiophene via ATRP[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2010,48(24):5670-5678.
APA Yang, Qian.,Jin, Hao.,Xu, Yiding.,Shen, Zhihao.,Fan, Xinghe.,...&Zhou, Qifeng.(2010).Electroluminescent Block Copolymers Containing Oxadiazole and Thiophene via ATRP.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,48(24),5670-5678.
MLA Yang, Qian,et al."Electroluminescent Block Copolymers Containing Oxadiazole and Thiophene via ATRP".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 48.24(2010):5670-5678.
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