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Thermoreversible Covalent Self-Assembly of Oligo(p-phenylenevinylene) Bridged Gold Nanoparticles
Liu, Xiaofeng1,3; Liu, Huibiao1; Zhou, Weidong1,3; Zheng, Haiyan1,3; Yin, Xiaodong1,3; Li, Yuliang1; Guo, Yanbing1,3; Zhu, Mei1,3; Ouyang, Canbin1,3; Zhu, Daoben1
刊名LANGMUIR
2010-03-02
卷号26期号:5页码:3179-3185
ISSN号0743-7463
DOI10.1021/la903838w
英文摘要Organic-inorganic have been fabricated through mild Diels-Alder cross-linking between maleimide bearing oligo(p-phenylenevinylene) (OPV) and furan functionalized gold nanoparticles with diameter smaller than 2 nm. The OPV ligands afford strong reaction ability toward furan group due to their maleimide moieties. These small gold nanoparticles form close-packed homogeneous hybrids with well-defined interfaces by incorporating OPV ligands in solutions. Covalent assembly and disassembly of gold nanoparticles can be achieved by repeated thermal stimuli on as-obtained hybrids, which can be monitored by fluorescence changes of OPVs and Surface plasmon resonance absorption. Moreover, the dramatic photophysical properties and assembly behavior of these hybrids allow this procedure to be performed as a smart assay for monitoring the process of the Diels-Alder reaction.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000274636900032
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/68681]  
专题中国科学院化学研究所
通讯作者Liu, Huibiao
作者单位1.Chinese Acad Sci, BNLMS, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, State Key Lab Mol React Dynam, Inst Chem, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Liu, Xiaofeng,Liu, Huibiao,Zhou, Weidong,et al. Thermoreversible Covalent Self-Assembly of Oligo(p-phenylenevinylene) Bridged Gold Nanoparticles[J]. LANGMUIR,2010,26(5):3179-3185.
APA Liu, Xiaofeng.,Liu, Huibiao.,Zhou, Weidong.,Zheng, Haiyan.,Yin, Xiaodong.,...&Xia, Andong.(2010).Thermoreversible Covalent Self-Assembly of Oligo(p-phenylenevinylene) Bridged Gold Nanoparticles.LANGMUIR,26(5),3179-3185.
MLA Liu, Xiaofeng,et al."Thermoreversible Covalent Self-Assembly of Oligo(p-phenylenevinylene) Bridged Gold Nanoparticles".LANGMUIR 26.5(2010):3179-3185.
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