Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water

doi:10.1039/b904305e

CORC > 化学研究所 > 中国科学院化学研究所

	Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water
	Cheng, Yan 1; Fan, Honglei 1; Wu, Suxiang 1; Wang, Qian 1; Guo, Jin 1,2; Gao, Liang 3; Zong, Baoning 3; Han, Buxing 1
刊名	GREEN CHEMISTRY
	2009
卷号	11 期号:7 页码:1061-1065
ISSN号	1463-9262
DOI	10.1039/b904305e
英文摘要	Enhancing selectivity and an efficient use of feedstocks in chemical reactions using greener methods is an important aspect of green chemistry. In this work, we conducted the hydrogenation of naphthalene to produce tetralin catalyzed by a cheap Fe-Mo based catalyst with and without high temperature water (HTW). The effects of various factors on the reaction, such as density of water, reaction temperature, reaction time and amounts of catalyst, were investigated. It was demonstrated that the addition of water could increase the yield of tetralin and suppress formation of coke effectively. The reaction in the presence of D(2)O indicated that H/D exchange occurred during the reaction process.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000267727800027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/68155]
专题	中国科学院化学研究所
通讯作者	Cheng, Yan
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.China Univ Min & Technol, Beijing 100190, Peoples R China 3.Res Inst Petr Proc, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	Cheng, Yan,Fan, Honglei,Wu, Suxiang,et al. Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water[J]. GREEN CHEMISTRY,2009,11(7):1061-1065.
APA	Cheng, Yan.,Fan, Honglei.,Wu, Suxiang.,Wang, Qian.,Guo, Jin.,...&Han, Buxing.(2009).Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water.GREEN CHEMISTRY,11(7),1061-1065.
MLA	Cheng, Yan,et al."Enhancing the selectivity of the hydrogenation of naphthalene to tetralin by high temperature water".GREEN CHEMISTRY 11.7(2009):1061-1065.