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Numerical simulation of coil-helix transition processes of gelatin
Chen, Xiliang1; Jia, Yuxi1; Feng, Ligang1; Sun, Sheng1; An, Lijia2
刊名POLYMER
2009-04-24
卷号50期号:9页码:2181-2189
关键词Structural Inhomogeneity Crosslinking Density Helix Length
ISSN号0032-3861
DOI10.1016/j.polymer.2009.02.039
英文摘要Gelatin is widely used in food, pharmaceutical, and photographic industries due to the coil-helix transition, whereas the structural inhomogeneity considerably affects its essential properties closely connecting with the industrial applications. The spatially structural inhomogeneity of the gelatin caused by the uneven and unstable temperature field is analyzed by the finite element method during the cooling-induced coil-helix transition process. The helix conversion and the crosslinking density as functions of time and spatial grid are calculated by the incremental method. A length distribution density function is introduced to describe the continuous length distributions of two kinds of triple helices. The results show that the crosslinking density and the length distribution of triple helices are dependent on the thermal histories. And the spatially structural inhomogeneity is more distinct when the initial gelatin concentration and the convective heat transfer coefficient increase. The present work is helpful for optimizing the fabrication conditions of gelatin. (C) 2009 Elsevier Ltd. All rights reserved.
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000265433700024
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/67455]  
专题中国科学院化学研究所
通讯作者Jia, Yuxi
作者单位1.Shandong Univ, Sch Mat Sci & Engn, Jinan 250061, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Chen, Xiliang,Jia, Yuxi,Feng, Ligang,et al. Numerical simulation of coil-helix transition processes of gelatin[J]. POLYMER,2009,50(9):2181-2189.
APA Chen, Xiliang,Jia, Yuxi,Feng, Ligang,Sun, Sheng,&An, Lijia.(2009).Numerical simulation of coil-helix transition processes of gelatin.POLYMER,50(9),2181-2189.
MLA Chen, Xiliang,et al."Numerical simulation of coil-helix transition processes of gelatin".POLYMER 50.9(2009):2181-2189.
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