A new series of lanthanide coordination polymers with 2,2 '-bipyridine and glutaric acid: Synthesis, crystal structures and properties of [Ln(bipy)(glut)(NO3)]

doi:10.1016/j.molstruc.2009.05.030

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	A new series of lanthanide coordination polymers with 2,2 '-bipyridine and glutaric acid: Synthesis, crystal structures and properties of [Ln(bipy)(glut)(NO3)]
	Wang, Chunguang 1; Xing, Yongheng 1; Li, Zhangpeng 1; Li, Jing 1; Zeng, Xiaoqing 2; Ge, Maofa 2; Niu, Shuyun 1
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2009-08-14
卷号	931 期号:1-3 页码:76-81
关键词	Lanthanide Coordination Polymer Synthesis Crystal Structure Thermal Stability Luminescent Property
ISSN号	0022-2860
DOI	10.1016/j.molstruc.2009.05.030
英文摘要	A series of new lanthanide coordination polymers, with the formula [Ln(bipy)(glut)(NO3)] (Ln = Eu (1), Tb (2), Sm (3), Pr (4); bipy = 2,2'-bipyridine: H(2)glut = glutaric acid), have been synthesized under the hydrothermal condition and characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, and single-crystal X-ray diffraction. Structural analyses reveal that all four complexes are isostructural and crystallized in monoclinic system, P2(1)/c space group. For these complexes, the Ln(3+) are all linked through glutaric acid ligands to form 1D chain-like polymeric structures, and bipy and NO3- are coordinated on two sides of the chains. The thermogravimetric analysis of 1 and photoluminescent properties of 1 and 2 are discussed in detail. (C) 2009 Elsevier B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000268608200012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/65845]
专题	中国科学院化学研究所
通讯作者	Xing, Yongheng
作者单位	1.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, Chunguang,Xing, Yongheng,Li, Zhangpeng,et al. A new series of lanthanide coordination polymers with 2,2 '-bipyridine and glutaric acid: Synthesis, crystal structures and properties of [Ln(bipy)(glut)(NO3)][J]. JOURNAL OF MOLECULAR STRUCTURE,2009,931(1-3):76-81.
APA	Wang, Chunguang.,Xing, Yongheng.,Li, Zhangpeng.,Li, Jing.,Zeng, Xiaoqing.,...&Niu, Shuyun.(2009).A new series of lanthanide coordination polymers with 2,2 '-bipyridine and glutaric acid: Synthesis, crystal structures and properties of [Ln(bipy)(glut)(NO3)].JOURNAL OF MOLECULAR STRUCTURE,931(1-3),76-81.
MLA	Wang, Chunguang,et al."A new series of lanthanide coordination polymers with 2,2 '-bipyridine and glutaric acid: Synthesis, crystal structures and properties of [Ln(bipy)(glut)(NO3)]".JOURNAL OF MOLECULAR STRUCTURE 931.1-3(2009):76-81.