One-pot synthesis and characterization of hyperbranched poly(ester-amide)s from commercially available dicarboxylic acids and multihydroxyl secondary Amines

doi:10.1002/pola.22836

CORC > 化学研究所 > 中国科学院化学研究所

	One-pot synthesis and characterization of hyperbranched poly(ester-amide)s from commercially available dicarboxylic acids and multihydroxyl secondary Amines
	Lin, Ying 1,2; Dong, Zhongmin 1,2; Li, Yuesheng 1
刊名	JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
	2008-08-01
卷号	46 期号:15 页码:5077-5092
关键词	Hyperbranched Modification Polycondensation Polyesters
ISSN号	0887-624X
DOI	10.1002/pola.22836
英文摘要	A convenient and cost-effective strategy for synthesis of hyperbranched poly(ester-amide)s from commercially available dicarboxylic acids (A(2)) and multihydroxyl secondary amine (CB2) has been developed. By optimizing the conditions of model reactions, the AB(2)-type intermediates were formed dominantly during the initial reaction stage. Without any purification, the AB(2) intermediate was subjected to thermal polycondensation in the absence of any catalyst to prepare the aliphatic and semiaromatic hyperbranched poly(ester-amide)s bearing multi-hydroxyl end-groups. The FTIR and H-1 NMR spectra indicated that the polymerization proceeded in the proposed way. The DBs of the resulting polymers were confirmed by a combination of inverse-gated decoupling C-13 NMR, and DEPT-135 NMR techniques. The DBs of the hyperbranched poly(ester-amide)s were in the range of 0.44-0.73, depending on the structure of the monomers used. The hyperbranched polymers exhibited moderate molecular weights with relatively broad distributions determined by SEC. All the polymers displayed low inherent viscosity (0.11-0.25 dL/g) due to the branched nature. Structural and end-group effects on the thermal properties of the hyperbranched polymers were investigated using DSC. The thermogravimetric analysis revealed that the resulting polymers exhibit reasonable thermal stability. (C) 2008 Wiley Periodicals, Inc.
语种	英语
出版者	JOHN WILEY & SONS INC
WOS记录号	WOS:000257915000012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/64935]
专题	中国科学院化学研究所
通讯作者	Li, Yuesheng
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun Branch, Changchun 130022, Peoples R China
推荐引用方式 GB/T 7714	Lin, Ying,Dong, Zhongmin,Li, Yuesheng. One-pot synthesis and characterization of hyperbranched poly(ester-amide)s from commercially available dicarboxylic acids and multihydroxyl secondary Amines[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2008,46(15):5077-5092.
APA	Lin, Ying,Dong, Zhongmin,&Li, Yuesheng.(2008).One-pot synthesis and characterization of hyperbranched poly(ester-amide)s from commercially available dicarboxylic acids and multihydroxyl secondary Amines.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,46(15),5077-5092.
MLA	Lin, Ying,et al."One-pot synthesis and characterization of hyperbranched poly(ester-amide)s from commercially available dicarboxylic acids and multihydroxyl secondary Amines".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 46.15(2008):5077-5092.