Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation

doi:10.1002/pola.22792

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	Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation
	Li, Weiwei 1; Han, Yang 1; Li, Binsong 1; Liu, Caiming 2; Bo, Zhishan 1
刊名	JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
	2008-07-01
卷号	46 期号:13 页码:4556-4563
关键词	Conducting Polymers Conjugated Polymers Polycondensation
ISSN号	0887-624X
DOI	10.1002/pola.22792
英文摘要	Zero-valent palladium complex, Pd(PTh3)(3), with three tri(2-thienyl)phosphine ligands was prepared and characterized. Pd(PTh3)(3) is superior to Pd(PPh3)(4) in catalyzing Suzuki-Miyaura coupling and polymerization of thiophene-based derivatives. The Suzuki polycondensation of 3-hexyl-5-iodothiophene-2-boronic pinacol ester with Pd(PTh3)(3) as the catalyst precursor afforded high-molecular-weight P3HT with high regularity and yield. (C) 2008 Wiley Periodicals, Inc.
语种	英语
出版者	JOHN WILEY & SONS INC
WOS记录号	WOS:000257153500027
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/64155]
专题	中国科学院化学研究所
通讯作者	Bo, Zhishan
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Li, Weiwei,Han, Yang,Li, Binsong,et al. Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2008,46(13):4556-4563.
APA	Li, Weiwei,Han, Yang,Li, Binsong,Liu, Caiming,&Bo, Zhishan.(2008).Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,46(13),4556-4563.
MLA	Li, Weiwei,et al."Tris[tri(2-thienyl)phosphine] palladium as the catalyst precursor for thiophene-based Suzuki-Miyaura crosscoupling and polycondensation".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 46.13(2008):4556-4563.