Synthesis and structural characterization of triphenyltin N-(5-chlorosalicylidene)-alpha-amino carboxylates

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	Synthesis and structural characterization of triphenyltin N-(5-chlorosalicylidene)-alpha-amino carboxylates
	Tian, Lai-Jin ; Liu, Xi-Cheng ; Mao, Wu-Tao ; Sun, Yu-Xi ; Liu, Xi-Jie ; Zhou, Zheng-Yu
刊名	CHINESE JOURNAL OF ORGANIC CHEMISTRY
	2007-10-01
卷号	27 期号:10 页码:1258-1263
关键词	Triphenyltin(Iv) 5-chlorosalicylic Aldehyde Alpha-amino Acid Schiff Base Crystal Structure
ISSN号	0253-2786
英文摘要	Triphenyltin salts of N-(5-chlorosalicylidene)-alpha-amino acid 1 similar to 6 were synthesized by the reaction of triphenyltin chloride with in situ formed Schiff base, potassium salt of N-(5-chlorosalicylidene)a-amino acid, and characterized by means of elemental analysis, IR and NMR spectra. The crystal structures of triphenyltin N-(5-chlorosalicylidene)valinate (3) and triphenyltin N-(5-chlorosalicylidene)-isoleucinate (5) were reported. The X-ray structures reveal that the tin atom is five-coordinated and adopts a polymeric trans-O2SnC3 trigonal bipyramidal configuration with the axial positions occupied by a carboxylate oxygen from the ligand and the phenolic oxygen of the ligand in an adjacent complex.
语种	英语
出版者	SCIENCE CHINA PRESS
WOS记录号	WOS:000250328000010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/61603]
专题	中国科学院化学研究所
通讯作者	Tian, Lai-Jin
作者单位	1.Qufu Normal Univ, Dept Chem, Qufu 273165, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
推荐引用方式 GB/T 7714	Tian, Lai-Jin,Liu, Xi-Cheng,Mao, Wu-Tao,et al. Synthesis and structural characterization of triphenyltin N-(5-chlorosalicylidene)-alpha-amino carboxylates[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2007,27(10):1258-1263.
APA	Tian, Lai-Jin,Liu, Xi-Cheng,Mao, Wu-Tao,Sun, Yu-Xi,Liu, Xi-Jie,&Zhou, Zheng-Yu.(2007).Synthesis and structural characterization of triphenyltin N-(5-chlorosalicylidene)-alpha-amino carboxylates.CHINESE JOURNAL OF ORGANIC CHEMISTRY,27(10),1258-1263.
MLA	Tian, Lai-Jin,et al."Synthesis and structural characterization of triphenyltin N-(5-chlorosalicylidene)-alpha-amino carboxylates".CHINESE JOURNAL OF ORGANIC CHEMISTRY 27.10(2007):1258-1263.