Polyaniline microtubes synthesized via supercritical CO2 and aqueous interfacial polymerization | |
Du, JM; Zhang, JL; Han, BX; Liu, ZM; Wan, MX | |
刊名 | SYNTHETIC METALS |
2005-12-15 | |
卷号 | 155期号:3页码:523-526 |
关键词 | Polyaniline Interfacial Polymerization Scco2 Xrd |
ISSN号 | 0379-6779 |
DOI | 10.1016/j.synthmet.2005.07.336 |
英文摘要 | We report a new route to prepare polyaniline (PANI) microtubes via supercritical (SC) CO2/aqueous interfacial polymerization. The synthesis is based on the well-known chemical oxidative polymerization of aniline in an acidic environment, with ammonium peroxydisufate (APS) as the oxidant, and sodium dodecyl sulfate (SDS) surfactant was used as the template. The main feature of this route is that the monomer (aniline) which is dissolved in SC CO2 phase, slowly polymerized at the interface of SC CO2 and aqueous solution to form the PANI microtubes. The morphologies, phase structure, composition and some properties of PANI microtubes were characterized by TEM, SEM, XRD, IR, XPS UV-vis and SYSTEM DM digital multimeter, respectively. (C) 2005 Elsevier B.V. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000234185700014 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/57309] |
专题 | 中国科学院化学研究所 |
通讯作者 | Han, BX |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Du, JM,Zhang, JL,Han, BX,et al. Polyaniline microtubes synthesized via supercritical CO2 and aqueous interfacial polymerization[J]. SYNTHETIC METALS,2005,155(3):523-526. |
APA | Du, JM,Zhang, JL,Han, BX,Liu, ZM,&Wan, MX.(2005).Polyaniline microtubes synthesized via supercritical CO2 and aqueous interfacial polymerization.SYNTHETIC METALS,155(3),523-526. |
MLA | Du, JM,et al."Polyaniline microtubes synthesized via supercritical CO2 and aqueous interfacial polymerization".SYNTHETIC METALS 155.3(2005):523-526. |
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