Aluminum Schiff base catalysts derived from beta-diketone for the stereoselective polymerization of racemic lactides

doi:10.1002/pola.21108

CORC > 化学研究所 > 中国科学院化学研究所

	Aluminum Schiff base catalysts derived from beta-diketone for the stereoselective polymerization of racemic lactides
	Pang, X ; Du, HZ ; Chen, XS ; Zhuang, XL ; Cui, DM ; Jing, XB
刊名	JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
	2005-12-15
卷号	43 期号:24 页码:6605-+
关键词	Biodegradable Crystal Structures Enolic Ring-opening Polymerization Stereoselective
ISSN号	0887-624X
DOI	10.1002/pola.21108
英文摘要	Two aluminum Schiff base catalysts with the formula LA1Et [L = bis(benzoylacetone)trimethylenediimine (1) or bis(benzoylacetone)ethylenediimine (2)] were designed and synthesized for a comparison of their catalytic properties in the polymerization of racemic lactides. Single-crystal data of catalyst 1 confirmed its trigonal bipyramidal configuration with a five-coordinated aluminum atom in the center. These catalysts were shown to be highly active and stereoselective for the controlled ring-opening polymerization of racemic lactides.
语种	英语
出版者	JOHN WILEY & SONS INC
WOS记录号	WOS:000233648700038
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/56613]
专题	中国科学院化学研究所
通讯作者	Chen, XS
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Pang, X,Du, HZ,Chen, XS,et al. Aluminum Schiff base catalysts derived from beta-diketone for the stereoselective polymerization of racemic lactides[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2005,43(24):6605-+.
APA	Pang, X,Du, HZ,Chen, XS,Zhuang, XL,Cui, DM,&Jing, XB.(2005).Aluminum Schiff base catalysts derived from beta-diketone for the stereoselective polymerization of racemic lactides.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,43(24),6605-+.
MLA	Pang, X,et al."Aluminum Schiff base catalysts derived from beta-diketone for the stereoselective polymerization of racemic lactides".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 43.24(2005):6605-+.