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Evolved structure of thiazolothiazole based small molecules towards enhanced efficiency in organic solar cells
Cheng, Pei1,2; Shi, Qinqin1; Lin, Yuze1,2; Li, Yongfang1; Zhan, Xiaowei1,3
刊名ORGANIC ELECTRONICS
2013-02-01
卷号14期号:2页码:599-606
关键词Thiazolothiazole Triphenylamine Small Molecule Organic Solar Cell Solution Process Structure-property Relationship
ISSN号1566-1199
DOI10.1016/j.orgel.2012.11.026
英文摘要Small molecule donors T0-T2 with thiazolothiazole as acceptor unit, triphenylamine as donor unit and thiophene with different number as bridge are synthesized. With increasing thiophene number and conjugation length, these molecules exhibit red-shifted absorption (300-600 nm), slightly up-shifted HOMO levels (-5.31 to -5.28 eV), slightly down-shifted LUMO levels (-2.64 to -2.75 eV), and reduced optical band gaps (2.55-2.11 eV). Solution processed organic solar cells based on T0-T2/PC71BM (1:4, w/w) after thermal annealing exhibit power conversion efficiency up to 2.19%, 3.73% and 4.05% under AM 1.5G illumination (100 mW/cm(2)), respectively. Effects of thermal annealing on morphology, charge transport and photovoltaic property of blend films are investigated. (C) 2012 Elsevier B.V. All rights reserved.
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000314658700024
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/54907]  
专题中国科学院化学研究所
通讯作者Zhan, Xiaowei
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Pei,Shi, Qinqin,Lin, Yuze,et al. Evolved structure of thiazolothiazole based small molecules towards enhanced efficiency in organic solar cells[J]. ORGANIC ELECTRONICS,2013,14(2):599-606.
APA Cheng, Pei,Shi, Qinqin,Lin, Yuze,Li, Yongfang,&Zhan, Xiaowei.(2013).Evolved structure of thiazolothiazole based small molecules towards enhanced efficiency in organic solar cells.ORGANIC ELECTRONICS,14(2),599-606.
MLA Cheng, Pei,et al."Evolved structure of thiazolothiazole based small molecules towards enhanced efficiency in organic solar cells".ORGANIC ELECTRONICS 14.2(2013):599-606.
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