Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy

doi:10.1007/s11434-013-5763-9

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	Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy
	Liu AnAn 1; Huang Zhi 1; Deng GangHua 2; Guo Yuan 3
刊名	CHINESE SCIENCE BULLETIN
	2013-05-01
卷号	58 期号:13 页码:1529-1535
关键词	Air/water Interface Sum Frequency Generation Adsorption Isotherm Benzonitrile
ISSN号	1001-6538
DOI	10.1007/s11434-013-5763-9
英文摘要	In this investigation, the adsorption of benzonitrile at the air/water interface was addressed using vibrational sum-frequency spectroscopy. Using ppp and ssp polarization combinations, the authors detected the symmetric stretching mode of the cyano (CN) group and calculated the orientation of benzonitrile at the interface. In addition, the adsorption isotherm was determined in terms of the hyperpolarizability element by varying the bulk benzonitrile concentration. The adsorption energy was obtained from fitting this isotherm. This work will add to our understanding of chemical processes relevant to retention, degradation, and photolysis of benzonitriles in the environment.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000318527200008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/54297]
专题	中国科学院化学研究所
通讯作者	Guo Yuan
作者单位	1.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Liu AnAn,Huang Zhi,Deng GangHua,et al. Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy[J]. CHINESE SCIENCE BULLETIN,2013,58(13):1529-1535.
APA	Liu AnAn,Huang Zhi,Deng GangHua,&Guo Yuan.(2013).Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy.CHINESE SCIENCE BULLETIN,58(13),1529-1535.
MLA	Liu AnAn,et al."Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy".CHINESE SCIENCE BULLETIN 58.13(2013):1529-1535.