The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst

doi:10.1002/cctc.201402671

CORC > 化学研究所 > 中国科学院化学研究所

	The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst
	Zhang, Peng; Wu, Tianbin; Hou, Minqiang; Ma, Jun; Liu, Huizhen; Jiang, Tao; Wang, Weitao; Wu, Congyi; Han, Buxing
刊名	CHEMCATCHEM
	2014-12-01
卷号	6 期号:12 页码:3323-3327
关键词	Arenes Hydrogenation Lewis Acids Palladium Surface Hydroxyl Groups
ISSN号	1867-3880
DOI	10.1002/cctc.201402671
英文摘要	Al2O3 or SiO2 particles with abundant surface hydroxyl groups can prevent side reactions of aromatic compounds with AlCl3 completely; this Lewis acid can potentially destroy the stable structure of aromatic compounds to a large extent. This discovery was successfully utilized in the highly efficient hydrogenation of benzene, toluene, and naphthalene under mild conditions co-catalyzed by AlCl3 and Pd/Al2O3 or Pd/SiO2. Pd, AlCl3, and the surface hydroxyl groups on the support show excellent cooperative effects for the hydrogenation reactions. Theoretical studies indicate that formation of a complex, by an interaction between benzene, AlCl3, and the solid oxides, plays a key role in the highly efficient hydrogenation reactions.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000345975300007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/53241]
专题	中国科学院化学研究所
通讯作者	Wu, Tianbin
作者单位	Chinese Acad Sci, CAS Key Lab Colloid & Interface & Thermodynam, Inst Chem, BNLMS, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Peng,Wu, Tianbin,Hou, Minqiang,et al. The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst[J]. CHEMCATCHEM,2014,6(12):3323-3327.
APA	Zhang, Peng.,Wu, Tianbin.,Hou, Minqiang.,Ma, Jun.,Liu, Huizhen.,...&Han, Buxing.(2014).The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst.CHEMCATCHEM,6(12),3323-3327.
MLA	Zhang, Peng,et al."The Hydrogenation of Aromatic Compounds under Mild Conditions by Using a Solid Lewis Acid and Supported Palladium Catalyst".CHEMCATCHEM 6.12(2014):3323-3327.