Fabrication of Binary Chiral Supramolecular Aggregates at the Air-Water Interface

doi:10.1166/sam.2014.2198

CORC > 化学研究所 > 中国科学院化学研究所

	Fabrication of Binary Chiral Supramolecular Aggregates at the Air-Water Interface
	Tang, Ying 1; Wang, Hui-Ting 1; Chen, Meng 1; Qian, Dong-Jin 1; Zhang, Li 2; Liu, Minghua 2
刊名	SCIENCE OF ADVANCED MATERIALS
	2014-11-01
卷号	6 期号:11 页码:2558-2561
关键词	Chiral Supramolecular Aggregate Langmuir-blodgett Film Porphyrin Coordination Polymer
ISSN号	1947-2935
DOI	10.1166/sam.2014.2198
英文摘要	Binary chiral supramolecular aggregates, composed of 5,10,15,20-(4-pyridyl) porphyrin (TPyP) and enantiomers of hydroquinine anthraquinone-1,4-diyl diether, (DHQ)(2)AQN or (DHQD)(2)AQN, have been prepared by the Langmuir-Blodgett (LB) technique. Mirror-imaged circular dichroism signals were recorded at about 242-266 and 424-442 nm; the former was designated (DHQ)(2)AQN and (DHQD)(2)AQN, while the latter was TPyP induced by the co-assembled (DHQ)(2)AQN or (DHQD)(2)AQN. The relative intensity of the chiral TPyP signals was largely enhanced in the LB films of Cu(II)/TPyP-(DHQ)(2)AQN and (DHQD)(2)AQN the of coordination polymers was prepared at the CuAc2 sub phase surface, suggesting that the coordination bonding of Cu-Py could efficiently induce the chirality of supramolecular aggregates.
语种	英语
出版者	AMER SCIENTIFIC PUBLISHERS
WOS记录号	WOS:000348431100051
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/51067]
专题	中国科学院化学研究所
通讯作者	Qian, Dong-Jin
作者单位	1.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Tang, Ying,Wang, Hui-Ting,Chen, Meng,et al. Fabrication of Binary Chiral Supramolecular Aggregates at the Air-Water Interface[J]. SCIENCE OF ADVANCED MATERIALS,2014,6(11):2558-2561.
APA	Tang, Ying,Wang, Hui-Ting,Chen, Meng,Qian, Dong-Jin,Zhang, Li,&Liu, Minghua.(2014).Fabrication of Binary Chiral Supramolecular Aggregates at the Air-Water Interface.SCIENCE OF ADVANCED MATERIALS,6(11),2558-2561.
MLA	Tang, Ying,et al."Fabrication of Binary Chiral Supramolecular Aggregates at the Air-Water Interface".SCIENCE OF ADVANCED MATERIALS 6.11(2014):2558-2561.