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Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films
Jiao, Tifeng1,2; Xing, Yuanyuan1; Zhang, Qingrui1; Zhang, Li3; Liu, Minghua3; Zhou, Jingxin1; Gao, Faming1
刊名JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
2014-06-01
卷号14期号:6页码:4400-4404
关键词Supramolecular Assembly Langmuir-blodgett Film Luminol Derivative Substituted Group Electrochemiluminescence Nanostructure
ISSN号1533-4880
DOI10.1166/jnn.2014.8056
英文摘要A series of functional luminol derivatives with aromatic and alkyl substituted groups has been designed and synthesized from the reaction of the corresponding chloride precursors with luminol. These compounds can be spread on water surface to form stable Langmuir films at the air-water interface. It has been found that UV and IR spectra confirmed the characteristic aromatic segment, imide group, and aromatic/alkyl substituted groups. In addition, for the interfacial assembly process of compounds with alkyl substituted groups, there are obvious spectral changes for the alkyl chains. AFM results indicated that various different aggregated domains may be fabricated in the transferred LB films. For all cases, the substituted groups in molecular structures have an important effect in regulating the aggregation mode and spectral changes in organized molecular films. The present results showed that the modified luminol derivatives may have potential application in functional material fields such as ECL sensor, which may give some insight to study the relationship between the molecular structures and supramolecular aggregation of amphiphiles in organized molecular films.
语种英语
出版者AMER SCIENTIFIC PUBLISHERS
WOS记录号WOS:000332339500060
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/50773]  
专题中国科学院化学研究所
通讯作者Jiao, Tifeng
作者单位1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Colloid & Interface Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Jiao, Tifeng,Xing, Yuanyuan,Zhang, Qingrui,et al. Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2014,14(6):4400-4404.
APA Jiao, Tifeng.,Xing, Yuanyuan.,Zhang, Qingrui.,Zhang, Li.,Liu, Minghua.,...&Gao, Faming.(2014).Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,14(6),4400-4404.
MLA Jiao, Tifeng,et al."Supramolecular Assembly and Nanostructures of a Series of Luminol Derivatives with Aromatic/Alkyl Substituted Groups in Langmuir-Blodgett Films".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 14.6(2014):4400-4404.
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