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Self-Assembly Behavior of a Linear-Star Supramolecular Amphiphile Based on Host-Guest Complexation
Wang, Juan1; Wang, Xing1; Yang, Fei1; Shen, Hong1; You, Yezi2; Wu, Decheng1
刊名LANGMUIR
2014-11-04
卷号30期号:43页码:13014-13020
ISSN号0743-7463
DOI10.1021/la503295z
英文摘要A star polymer, beta-cyclodextrin-poly(l-lactide) (beta-CD-PLLA), and a linear polymer, azobenzene-poly(ethylene glycol) (Azo-PEG), could self-assemble into a supramolecular amphiphilic copolymer (beta-CD-PLLA@Azo-PEG) based on the host-guest interaction between beta-CD and azobenzene moieties. This linear-star supramolecular amphiphilic copolymer further self-assembled into a variety of morphologies, including sphere-like micelle, carambola-like micelle, naan-like micelle, shuttle-like lamellae, tube-like fiber, and random curled-up lamellae, by tuning the length of hydrophilic or hydrophobic chains. The variation of morphology was closely related to the topological structure and block ratio of the supramolecular amphiphiles. These self-assembly structures could disassemble upon an ultraviolet (UV) light irradiation.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000343951000035
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/50521]  
专题中国科学院化学研究所
通讯作者Wu, Decheng
作者单位1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Univ Sci & Technol China, Dept Polymer Sci & Engn, Chinese Acad Sci CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Wang, Juan,Wang, Xing,Yang, Fei,et al. Self-Assembly Behavior of a Linear-Star Supramolecular Amphiphile Based on Host-Guest Complexation[J]. LANGMUIR,2014,30(43):13014-13020.
APA Wang, Juan,Wang, Xing,Yang, Fei,Shen, Hong,You, Yezi,&Wu, Decheng.(2014).Self-Assembly Behavior of a Linear-Star Supramolecular Amphiphile Based on Host-Guest Complexation.LANGMUIR,30(43),13014-13020.
MLA Wang, Juan,et al."Self-Assembly Behavior of a Linear-Star Supramolecular Amphiphile Based on Host-Guest Complexation".LANGMUIR 30.43(2014):13014-13020.
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