Water as an additive to enhance the ring opening of naphthalene

doi:10.1039/c2gc16554f

CORC > 化学研究所 > 中国科学院化学研究所

	Water as an additive to enhance the ring opening of naphthalene
	Wang, Qian; Fan, Honglei; Wu, Suxiang; Zhang, Zhaofu; Zhang, Peng; Han, Buxing
刊名	GREEN CHEMISTRY
	2012
卷号	14 期号:4 页码:1152-1158
ISSN号	1463-9262
DOI	10.1039/c2gc16554f
英文摘要	Use of water as a reaction medium or additive to enhance reaction efficiency is an important topic in green chemistry, and ring opening and contraction reactions of aromatics are crucial for upgrading diesels. In this work, we investigated the effect of water on the yields of ring opening and contraction reactions of naphthalene. A series of catalysts, such as Rh2O3/HY zeolite, Mo-Ni oxide and their physical mixtures, were used as the catalysts. The influences of the amount of water, hydrogen pressure, reaction temperature and reaction time on the yields of the ring opening and contraction products (ROCP) were studied. It was found that Rh2O3/HY and Mo-Ni oxide showed an excellent synergistic effect for catalyzing the reaction, and water could be used as a green and efficient additive for enhancing the yield of the ROCP. At the optimized conditions, the yield of the ROCP could be as high as 63.3%. The mechanism for the effect of water on the reactions was discussed on the basis of control experiments.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000302018600041
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/47973]
专题	中国科学院化学研究所
通讯作者	Wang, Qian
作者单位	Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, Qian,Fan, Honglei,Wu, Suxiang,et al. Water as an additive to enhance the ring opening of naphthalene[J]. GREEN CHEMISTRY,2012,14(4):1152-1158.
APA	Wang, Qian,Fan, Honglei,Wu, Suxiang,Zhang, Zhaofu,Zhang, Peng,&Han, Buxing.(2012).Water as an additive to enhance the ring opening of naphthalene.GREEN CHEMISTRY,14(4),1152-1158.
MLA	Wang, Qian,et al."Water as an additive to enhance the ring opening of naphthalene".GREEN CHEMISTRY 14.4(2012):1152-1158.