Effect of a novel self-assembly based on coordination polymer with zinc porphyrin in supramolecular solar cells

doi:10.1016/j.orgel.2013.07.033

CORC > 化学研究所 > 中国科学院化学研究所

	Effect of a novel self-assembly based on coordination polymer with zinc porphyrin in supramolecular solar cells
	Cao, Jing 1,2,3; Liu, Jia-Cheng 1,2,3; Deng, Wen-Ting 1,2,3; Li, Ren-Zhi 4; Jin, Neng-Zhi 5
刊名	ORGANIC ELECTRONICS
	2013-11-01
卷号	14 期号:11 页码:2713-2720
关键词	Self-assembly Coordination Polymer Zinc Porphyrin Solar Cell
ISSN号	1566-1199
DOI	10.1016/j.orgel.2013.07.033
英文摘要	Within this work, we firstly report the self-assemblies of zinc porphyrin coordination polymers (CPs) appended isonicotinic acid ligands by metal-ligand axial coordination approach immobilized on the nanostructured TiO2 electrode surfaces in photoelectrochemical devices. Compared to the assemblies based on zinc porphyrins integrated isonicotinic acid ligands via metal-ligand axial coordination or metal-ligand edged binding approach, the CPs-based assemblies exhibit significantly improved photovoltaic performances. Especially, the assembly based on iminazole-substituted zinc porphyrin coordination polymer exhibits an excellent photovoltaic performance with a short circuit photocurrent density (J(sc)) of 3.8 mA cm(-2), an open circuit voltage (V-oc) of 0.31 V, a fill factor (FF) of 0.67 and an overall conversion efficiency (eta) of 0.48% under AM 1.5 conditions. The results serve as another good testing ground for the fabrication of supramolecular devices techniques in future. (C) 2013 Elsevier B. V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000325487000001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/46419]
专题	中国科学院化学研究所
通讯作者	Liu, Jia-Cheng
作者单位	1.Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China 2.Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Polymer Mat Gansu Prov, Lanzhou 730070, Peoples R China 3.Northwest Normal Univ, Coll Chem & Chem Engn, Key Lab Bioelectrochem & Environm Anal Gansu Prov, Lanzhou 730070, Peoples R China 4.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 5.Gansu Comp Ctr, Lanzhou 730030, Peoples R China
推荐引用方式 GB/T 7714	Cao, Jing,Liu, Jia-Cheng,Deng, Wen-Ting,et al. Effect of a novel self-assembly based on coordination polymer with zinc porphyrin in supramolecular solar cells[J]. ORGANIC ELECTRONICS,2013,14(11):2713-2720.
APA	Cao, Jing,Liu, Jia-Cheng,Deng, Wen-Ting,Li, Ren-Zhi,&Jin, Neng-Zhi.(2013).Effect of a novel self-assembly based on coordination polymer with zinc porphyrin in supramolecular solar cells.ORGANIC ELECTRONICS,14(11),2713-2720.
MLA	Cao, Jing,et al."Effect of a novel self-assembly based on coordination polymer with zinc porphyrin in supramolecular solar cells".ORGANIC ELECTRONICS 14.11(2013):2713-2720.