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Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives
Xiong, Wei1,2; Zhu, Qijian1,2; Gong, Yanjun1,2; Wang, Chen3; Che, Yanke1,2; Zhao, Jincai1,2
刊名ANALYTICAL CHEMISTRY
2018-04-03
卷号90期号:7页码:4273-4276
ISSN号0003-2700
DOI10.1021/acs.analchem.8b00556
英文摘要In this work, we develop a sequential self-assembly approach to fabricate interpenetrated binary supramolecular nanofibers consisting of carbazole oligomer 1-cobalt(II) (1-Co2+) coordination nanofibers and oligomer 2 nanofibers for the sensitive detection of six classes of explosives. When exposed to peroxide explosives (e.g., H2O2), Co2+ in 1-Co2+ coordination nanofibers can be reduced to Co+ that can transfer an electron to the excited 2 nanofibers and thereby quench their fluorescence. On the other hand, when exposed to the other five classes of explosives, the excited 2 nanofibers can transfer an electron to explosives to quench their fluorescence. On the basis of the distinct fluorescence quenching mechanisms, six classes of explosives can be sensitively detected. Herein, we provide a new strategy to design broad-band fluorescence sensors for a rich identification of threats.
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000429385800007
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/46089]  
专题中国科学院化学研究所
通讯作者Che, Yanke
作者单位1.Chinese Acad Sci, CAS Res Educat Ctr Excellence Mol Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.HT NOVA Co Ltd, Zhuyuan Rd, Beijing 101312, Peoples R China
推荐引用方式
GB/T 7714
Xiong, Wei,Zhu, Qijian,Gong, Yanjun,et al. Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives[J]. ANALYTICAL CHEMISTRY,2018,90(7):4273-4276.
APA Xiong, Wei,Zhu, Qijian,Gong, Yanjun,Wang, Chen,Che, Yanke,&Zhao, Jincai.(2018).Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives.ANALYTICAL CHEMISTRY,90(7),4273-4276.
MLA Xiong, Wei,et al."Interpenetrated Binary Supramolecular Nanofibers for Sensitive Fluorescence Detection of Six Classes of Explosives".ANALYTICAL CHEMISTRY 90.7(2018):4273-4276.
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