Study on the microstructure evolution of TiO2-reinforced HDPE nanocomposites by synchrotron small angle X-ray scattering | |
Li, Xiaoyun1; Liu, Guoming2; Tang, Zhongfeng1; Zhang, Xiuqin2; Zhou, Ping1; Wang, Jie1; Li, Xiuhong1; Li, Liangbin3,4 | |
刊名 | POLYMER COMPOSITES |
2018-02-01 | |
卷号 | 39期号:2页码:580-587 |
ISSN号 | 0272-8397 |
DOI | 10.1002/pc.23971 |
英文摘要 | This work studies the effect of titanium dioxide (TiO2) nanoparticles on mechanical properties, thermal behavior and microstructures of high-density polyethylene (HDPE). Differential scanning calorimetry (DSC) results showed that melting temperature and crystallinity of the nanocomposites are affected by incorporating TiO2; the crystallinity reaches maximum at low TiO2 loading following with a significant reduction when the content of TiO2 higher than 2 wt%. To deeply understand structure-property relationship, SAXS experiments were carried out. The results indicated that the nanoparticles were homogeneously distributed in the HDPE matrix. The TiO2 nanoparticles exhibit surface-fractal characteristic at small scale. At large scale, with TiO2 content increasing, TiO2 clusters grow gradually until 2 wt%. The optimum microstructures and mechanical properties of HDPE/TiO2 nanocomposites were achieved at about 2 wt% loading. POLYM. COMPOS., 39:580-587, 2018. (c) 2016 Society of Plastics Engineers |
语种 | 英语 |
出版者 | WILEY |
WOS记录号 | WOS:000424842300030 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/45657] |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Xiaoyun |
作者单位 | 1.Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Engn Plast, Beijing, Peoples R China 3.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei, Anhui, Peoples R China 4.Univ Sci & Technol China, Coll Nucl Sci & Technol, Hefei, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Xiaoyun,Liu, Guoming,Tang, Zhongfeng,et al. Study on the microstructure evolution of TiO2-reinforced HDPE nanocomposites by synchrotron small angle X-ray scattering[J]. POLYMER COMPOSITES,2018,39(2):580-587. |
APA | Li, Xiaoyun.,Liu, Guoming.,Tang, Zhongfeng.,Zhang, Xiuqin.,Zhou, Ping.,...&Li, Liangbin.(2018).Study on the microstructure evolution of TiO2-reinforced HDPE nanocomposites by synchrotron small angle X-ray scattering.POLYMER COMPOSITES,39(2),580-587. |
MLA | Li, Xiaoyun,et al."Study on the microstructure evolution of TiO2-reinforced HDPE nanocomposites by synchrotron small angle X-ray scattering".POLYMER COMPOSITES 39.2(2018):580-587. |
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