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TiO2 nanoscale ionic materials using mussel adhesive proteins inspired ligand
Wu, Junjie1; Li, Dongdong2; Zeng, Huifang1; Zhou, Zhou1; Yang, Shijia2; Zhao, Ning2; Xu, Jian2
刊名APPLIED SURFACE SCIENCE
2018-11-30
卷号459页码:606-611
关键词Nanoscale Ionic Materials Bioinspired Mussel Titanium Dioxide Tiron
ISSN号0169-4332
DOI10.1016/j.apsusc.2018.08.039
英文摘要Inspired by mussel adhesive proteins, solvent-free nanoscale ionic materials (NIMs) were prepared using Tiron as bridging ligand, which could coordinate with titanium dioxide nanoparticles (TiO2 NPs) through ligand exchange, and then bridged with nonylphenyl poly(ethylene glycol) quaternary ammonium salt via ion exchange. The obtained homogenous TiO2-NIMs showed liquid-like behavior at room temperature. UV-visible and FT-IR spectra confirmed the coordination interaction between Tiron and TiO2 NPs. The size and crystal structure of TiO2 NPs were preserved during the modification. The well dispersion of NPs in the organic component, and the high content, low crystallization and melting temperature of the organic component guaranteed the unique properties of TiO2-NIMs. Moreover, TiO2-NIMs showed amphiphilic nature with good solubility and long-term stability in polar and nonpolar solvents. This research offers a useful and versatile approach to prepare NIMs and expands the gallery of bio-inspired materials.
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000444600300076
内容类型期刊论文
源URL[http://ir.iccas.ac.cn/handle/121111/43065]  
专题中国科学院化学研究所
通讯作者Zhao, Ning; Xu, Jian
作者单位1.State Grid Hunan Elect Power Co Ltd Res Inst, Changsha 410007, Hunan, Peoples R China
2.Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Wu, Junjie,Li, Dongdong,Zeng, Huifang,et al. TiO2 nanoscale ionic materials using mussel adhesive proteins inspired ligand[J]. APPLIED SURFACE SCIENCE,2018,459:606-611.
APA Wu, Junjie.,Li, Dongdong.,Zeng, Huifang.,Zhou, Zhou.,Yang, Shijia.,...&Xu, Jian.(2018).TiO2 nanoscale ionic materials using mussel adhesive proteins inspired ligand.APPLIED SURFACE SCIENCE,459,606-611.
MLA Wu, Junjie,et al."TiO2 nanoscale ionic materials using mussel adhesive proteins inspired ligand".APPLIED SURFACE SCIENCE 459(2018):606-611.
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