Cs2Zn5(PO4)(4) and Cs3La(PO4)(2): Two Cs-Containing Phosphates with Three-Dimensional Frameworks

doi:10.1002/ejic.201900241

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Cs2Zn5(PO4)(4) and Cs3La(PO4)(2): Two Cs-Containing Phosphates with Three-Dimensional Frameworks
	Guo, FJ (Guo, Fengjiao)[ 1,2 ]; Han, J (Han, Jian)[ 1 ]; Cheng, JN (Cheng, Jianian)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Abudouwufu, T (Abudouwufu, Tushagu)[ 1 ]; Yu, HW (Yu, Hongwei)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ]
刊名	EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
	2019
期号	19 页码:2462-2467
关键词	Cesium Phosphates Doping Luminescence Structure elucidation
ISSN号	1434-1948
DOI	10.1002/ejic.201900241
英文摘要	Two phosphates, Cs2Zn5(PO4)(4) and Cs3La(PO4)(2) have been successfully synthesized by employing the conventional solid-state reaction method, and their structures were determined by single-crystal X-ray diffraction. Cs2Zn5(PO4)(4) owns a three-dimensional (3)(infinity)[Zn4P4O16] framework and Cs3La(PO4)(2) features (2)(infinity)[La3P6O29] layers spreading in the bc plane. Infrared spectroscopy, UV/Vis-NIR diffuse reflectance spectroscopy were performed. The thermal properties and electronic structures of two compounds were investigated. In addition, the Ce3+ doped Cs3La(PO4)(2) phosphor was synthesized and its photoluminescence was analyzed. The results indicate that the Cs2Zn5(PO4)(4):0.01Ce(3+) phosphor can be excited by ultraviolet light to obtain blue luminescence.
WOS记录号	WOS:000468964200011
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/5760]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
通讯作者	Pan, SL (Pan, Shilie)[ 1 ]
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Guo, FJ ,Han, J ,Cheng, JN ,et al. Cs2Zn5(PO4)(4) and Cs3La(PO4)(2): Two Cs-Containing Phosphates with Three-Dimensional Frameworks[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2019(19):2462-2467.
APA	Guo, FJ .,Han, J .,Cheng, JN .,Yang, ZH .,Abudouwufu, T .,...&Pan, SL .(2019).Cs2Zn5(PO4)(4) and Cs3La(PO4)(2): Two Cs-Containing Phosphates with Three-Dimensional Frameworks.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(19),2462-2467.
MLA	Guo, FJ ,et al."Cs2Zn5(PO4)(4) and Cs3La(PO4)(2): Two Cs-Containing Phosphates with Three-Dimensional Frameworks".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .19(2019):2462-2467.