Alkali resistance promotion of Ce-doped vanadium-titanic-based NH3-SCR catalysts
Yan, Zidi; Shi, Xiaoyan; Yu, Yunbo; He, Hong
刊名JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
2018-11-01
卷号73页码:155-161
关键词Selective catalytic reduction Ammonia Nitrogen oxides V2O5/WO3-TiO2 Alkali deactivation
ISSN号1001-0742
文献子类Article
英文摘要The effect of K deactivation on V2O5/WO3-TiO2 and Ce-doped V2O5/WO3-TiO2 catalysts in the selective catalytic reduction (SCR) of NOx by NH3 was studied. Ce-doped V2O5/WO3-TiO(2)showed significantly higher resistance to K deactivation than V2O5/WO3-TiO2. Ce-doped V2O5/WO3-TiO2 with K/V = 4 (molar ratio) showed 90% NOx conversion at 350 degrees C, whereas in this case V2O5/WO3-TiO2 showed no activity. The fresh and K-poisoned V2O5/WO3-TiO2 and Ce-doped V2O5/WO3-TiO(2 )catalysts were investigated by means of in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), NH3-temperature progress decomposition (NH3-TPD), X-ray photoelectron spectroscopy (XPS) and H-2-temperature program reduction (H-2-TPR). The effect of Ce doping on the improving resistance to K of V2O5/WO3-TiO2 were discussed. (C) 2018 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.
内容类型期刊论文
源URL[http://ir.rcees.ac.cn/handle/311016/40798]  
专题生态环境研究中心_大气污染控制中心
推荐引用方式
GB/T 7714
Yan, Zidi,Shi, Xiaoyan,Yu, Yunbo,et al. Alkali resistance promotion of Ce-doped vanadium-titanic-based NH3-SCR catalysts[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2018,73:155-161.
APA Yan, Zidi,Shi, Xiaoyan,Yu, Yunbo,&He, Hong.(2018).Alkali resistance promotion of Ce-doped vanadium-titanic-based NH3-SCR catalysts.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,73,155-161.
MLA Yan, Zidi,et al."Alkali resistance promotion of Ce-doped vanadium-titanic-based NH3-SCR catalysts".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 73(2018):155-161.
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