Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites

CORC > 生态环境研究中心 > 中国科学院生态环境研究中心 > 环境化学与生态毒理学国家重点实验室

	Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites
	Liu, Aifeng; Zhao, Zongshan; Qu, Guangbo; Shen, Zhaoshuang; Shi, Jianbo; Jiang, Guibin
刊名	ENVIRONMENTAL POLLUTION
	2018-01-12
卷号	243 页码:1141-1153
关键词	TBBPA TBBPA derivatives Degradation Transformation Decomposition
ISSN号	0269-7491
文献子类	Review
英文摘要	Although the abiotic and biotic transformation/degradation (T/D) processes of tetrabromobisphenol A (TBBPA) have been widely investigated in model experiments, few reviews have focused on these processes along with their metabolites or degradation products. In this paper, we summarize the current knowledge on the T/D of TBBPA and its derivatives, including abiotic and biotic T/D strategies/conditions, mechanisms, metabolites and environmental occurrences. Various treatments, such as pyrolysis, photolysis, chemical reactions and biotransformation, have been employed to study the metabolic mechanism of TBBPA and its derivatives and to remediate associated contaminated environments. To date, more than 100 degradation products and metabolites have been identified, dominated by less brominated compounds such as bisphenol A, 2,6-dibromo-4-isopropylphenol, 2,6-dibromo-4-hydroxylphenol, 2,6-dibromophenol, isopropylene-2,6-dibromophenol, 4-(2-hydroxyisopropyl)-2,6-dibromophenol, etc. It can be concluded that the T/D of TBBPA mainly takes place through debromination and beta-scission. In some environmental media and human and animal tissues, brominated metabolites, glucoside and sulfate derivatives are also important T/D products. Here, the T/D products of TBBPA and its derivatives have been most comprehensively presented from the literature in recent 20 years. This review will enhance the understanding of the environmental behaviors of TBBPA-associated brominated flame retardants along with their ecological and health risks. (C) 2018 Elsevier Ltd. All rights reserved.
内容类型	期刊论文
源URL	[http://ir.rcees.ac.cn/handle/311016/41077]
专题	生态环境研究中心_环境化学与生态毒理学国家重点实验室
推荐引用方式 GB/T 7714	Liu, Aifeng,Zhao, Zongshan,Qu, Guangbo,et al. Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites[J]. ENVIRONMENTAL POLLUTION,2018,243:1141-1153.
APA	Liu, Aifeng,Zhao, Zongshan,Qu, Guangbo,Shen, Zhaoshuang,Shi, Jianbo,&Jiang, Guibin.(2018).Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites.ENVIRONMENTAL POLLUTION,243,1141-1153.
MLA	Liu, Aifeng,et al."Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites".ENVIRONMENTAL POLLUTION 243(2018):1141-1153.