Study on pollution behavior and sulfate formation during the typical haze event in Nanjing with water soluble inorganic ions and sulfur isotopes

doi:10.1016/j.atmosres.2018.11.009

	Study on pollution behavior and sulfate formation during the typical haze event in Nanjing with water soluble inorganic ions and sulfur isotopes
	Guo, Ziyan 1,2; Guo, Qingjun 3; Chen, Shanli 1,4; Zhu, Bin 4; Zhang, Yanlin 5; Yu, Jianghua 1,2; Guo, Zhaobing 2
刊名	ATMOSPHERIC RESEARCH
	2019-03-01
卷号	217 页码:198-207
关键词	Haze Water soluble inorganic ions Sulfur isotope Sulfate formation
ISSN号	0169-8095
DOI	10.1016/j.atmosres.2018.11.009
通讯作者	Guo, Zhaobing(guozbnuist@163.com)
英文摘要	The typical haze event in Nanjing was selected to study pollution behavior and sulfate formation by field measurement. Based on the concentrations of water soluble inorganic ions in PM2.5, pollution characteristics of the haze were investigated with phase clustering analysis. Besides, delta S-34 values of SO2 and sulfate in PM2.5 were determined in order to explore sulfur sources and sulfate formation. The result showed that PM2.5 pollution during the haze event was significantly serious, which was mainly from coal combustion, vehicle exhaust emission and biomass burning. Sulfate formation was attributed to aqueous phase sulfur oxidation reactions promoted by high relative humidity and NO2 concentration under the alkaline condition. The color of sky on 22 Dec. was ascribed to the combination of sunset glow and fine particles in high-moisture atmosphere. delta S-34 values of SO2 are found to be lower than those of sulfate in PM2.5 indicating there was presence of sulfur isotopic fractionation during SO2 oxidation. The average contribution of SO2 homogenous oxidation to sulfate was about 51.2% during the haze events. The ratio of SO2 heterogeneous and homogeneous oxidation to sulfate was mainly attributed to the concentrations of gaseous pollutants (NO2, SO2 and O-3) and relative humidity of the atmosphere.
资助项目	National Natural Science Foundation of China[41873016] ; National Natural Science Foundation of China[41625006] ; National Natural Science Foundation of China[91544229-02] ; National Natural Science Foundation of China[41373023] ; Jiangsu Province 333 Talent Project ; Jiangsu Province Qing Lan Project ; Priority Academic Program Development of Jiangsu Higher Education Institutions
WOS关键词	CHINESE SPRING FESTIVAL ; GAS-PHASE OXIDATION ; YANGTZE-RIVER DELTA ; CHEMICAL CHARACTERISTICS ; SOURCE APPORTIONMENT ; AIR-POLLUTION ; PARTICULATE MATTER ; ATMOSPHERIC PM2.5 ; AEROSOL-PARTICLES ; WINTER HAZE
WOS研究方向	Meteorology & Atmospheric Sciences
语种	英语
出版者	ELSEVIER SCIENCE INC
WOS记录号	WOS:000452931100019
资助机构	National Natural Science Foundation of China ; Jiangsu Province 333 Talent Project ; Jiangsu Province Qing Lan Project ; Priority Academic Program Development of Jiangsu Higher Education Institutions
内容类型	期刊论文
源URL	[http://ir.igsnrr.ac.cn/handle/311030/51438]
专题	中国科学院地理科学与资源研究所
通讯作者	Guo, Zhaobing
作者单位	1.Collaborat Innovat Ctr Atmospher Environm & Equip, Nanjing 210044, Jiangsu, Peoples R China 2.Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Nanjing 210044, Jiangsu, Peoples R China 3.Chinese Acad Sci, Inst Geog Sci & Nat Resources Res, Ctr Environm Remediat, Beijing 100101, Peoples R China 4.Nanjing Univ Informat Sci & Technol, Sch Atmospher Phys, Nanjing 210044, Jiangsu, Peoples R China 5.Nanjing Univ Informat Sci & Technol, Yale NUIST Ctr Atmospher Environm, Nanjing 210044, Jiangsu, Peoples R China
推荐引用方式 GB/T 7714	Guo, Ziyan,Guo, Qingjun,Chen, Shanli,et al. Study on pollution behavior and sulfate formation during the typical haze event in Nanjing with water soluble inorganic ions and sulfur isotopes[J]. ATMOSPHERIC RESEARCH,2019,217:198-207.
APA	Guo, Ziyan.,Guo, Qingjun.,Chen, Shanli.,Zhu, Bin.,Zhang, Yanlin.,...&Guo, Zhaobing.(2019).Study on pollution behavior and sulfate formation during the typical haze event in Nanjing with water soluble inorganic ions and sulfur isotopes.ATMOSPHERIC RESEARCH,217,198-207.
MLA	Guo, Ziyan,et al."Study on pollution behavior and sulfate formation during the typical haze event in Nanjing with water soluble inorganic ions and sulfur isotopes".ATMOSPHERIC RESEARCH 217(2019):198-207.