Synthesis of micro-mesoporous molecular sieve ZSM-5/SBA-15: tuning aluminium content for tert-butylation of phenol

doi:10.1007/s12039-019-1619-4

	Synthesis of micro-mesoporous molecular sieve ZSM-5/SBA-15: tuning aluminium content for tert-butylation of phenol
	Xu, Ling 1; Zhang, Qiang 1; Zhang, Miao 1; Mao, Lili 1; Hu, Jing 1; Liu, Zongrui 1; Xie, Yan 2
刊名	JOURNAL OF CHEMICAL SCIENCES
	2019-05-01
卷号	131 期号:5 页码:11
关键词	SBA-15 ZSM-5 micro-mesoporous molecular sieve phenol tert-butylylation
ISSN号	0974-3626
DOI	10.1007/s12039-019-1619-4
通讯作者	Liu, Zongrui(liuzr716@163.com) ; Xie, Yan(yanxie@dicp.ac.cn)
英文摘要	Micro-mesoporous ZSM-5/SBA-15 molecular sieve was derived from mesoporous molecular sieves SBA-15 by hydrothermal crystallization approach. The silica-alumina ratio significantly affects the structure and catalytic performance of ZSM-5/SBA-15. When the nSi/nAl is less than 25, the two-dimensional hexagonal pore structure of SBA-15 keeps intact with relatively low crystallinity of the pore wall. However, when the nSi/nAl is larger than 50, the SBA-15 pores are severely damaged. When nSi/nAl is 25, the catalyst ZSM-5/SBA-15 retains relatively good pore structure and shows excellent catalytic performance with 96.2% phenol conversion and 53.5% selectivity to 2,4-ditert-butyl phenol in the tert-butylation of phenol.Graphical Abstract SYNOPSIS Micro-mesoporous ZSM-5/SBA-15 molecular sieve was derived from mesoporous molecular sieve SBA-15 by hydrothermal crystallization approach. ZSM-5/SBA-15 (nSi/nAl=25) retains relatively good pore structure and shows excellent catalytic performance with 96.2% phenol conversion and 53.5% selectivity to 2,4-ditert-butyl phenol in the tert-butylation of phenol.
资助项目	National Natural Science Foundation of China[21561024] ; National Natural Science Foundation of China[21661026] ; National Natural Science Foundation of China[21606219]
WOS关键词	CATALYTIC PERFORMANCE ; T-BUTYLATION ; ZEOLITE-Y ; ALKYLATION ; SBA-15 ; ALCOHOL ; MCM-41 ; ADSORPTION ; TEMPLATE ; ZIRCONIA
WOS研究方向	Chemistry
语种	英语
出版者	INDIAN ACAD SCIENCES
WOS记录号	WOS:000467598500003
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171903]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Liu, Zongrui; Xie, Yan
作者单位	1.Inner Mongolia Univ Nationalities, Coll Chem & Chem Engn, Tongliao Inner Mongolia 028000, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Gold Catalysis Res Ctr, 457 Zhongshan Rd, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Xu, Ling,Zhang, Qiang,Zhang, Miao,et al. Synthesis of micro-mesoporous molecular sieve ZSM-5/SBA-15: tuning aluminium content for tert-butylation of phenol[J]. JOURNAL OF CHEMICAL SCIENCES,2019,131(5):11.
APA	Xu, Ling.,Zhang, Qiang.,Zhang, Miao.,Mao, Lili.,Hu, Jing.,...&Xie, Yan.(2019).Synthesis of micro-mesoporous molecular sieve ZSM-5/SBA-15: tuning aluminium content for tert-butylation of phenol.JOURNAL OF CHEMICAL SCIENCES,131(5),11.
MLA	Xu, Ling,et al."Synthesis of micro-mesoporous molecular sieve ZSM-5/SBA-15: tuning aluminium content for tert-butylation of phenol".JOURNAL OF CHEMICAL SCIENCES 131.5(2019):11.