Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials

doi:10.1021/acsami.9b02418

	Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials
	Chen, Shuqin 2,3; Gao, Jianmei 2,3; Chang, Junyu 2,3; Li, Yanqi 2,3; Huangfu, Changxin 2,3; Meng, Hu 3; Wang, Yu 3; Xia, Guangjie 1,4; Feng, Liang 3
刊名	ACS APPLIED MATERIALS & INTERFACES
	2019-05-15
卷号	11 期号:19 页码:17513-17520
关键词	hybrids materials copper(I) halide clusters tetra-alkylammonium cation copper(I) bromide amines sensing
ISSN号	1944-8244
DOI	10.1021/acsami.9b02418
通讯作者	Feng, Liang(fengl@dicp.ac.cn)
英文摘要	While a number of highly luminescent copper-(I) halide based hybrid materials built on coordinate bonds (Cu-L; L = N, P, S-based ligands) have been obtained, the poor structural stability largely limited their commercialization. In contrast, according to the previous studies, the ionic structures (L-free) are more stable than those built on Cu-L coordinate bonds. However, the extremely weak emission hinders their optical applications. Herein, we report a tetra-alkylammonium-cation-induced strategy for the synthesis of stable and highly luminescent ionic CuBr-based hybrid materials. It is interesting to find that the tetra-alkylammonium cations with different chains could induce diverse CuBr-based anions. Moreover, most of these CuBr-based hybrids are highly luminescent, which makes them promising candidates as an alternative to phosphors and with potential applications in sensing.
资助项目	National Natural Science Foundation of China[21605141] ; National Natural Science Foundation of China[21804132] ; Dalian Institute of Chemical Physics[DICP ZZBS201802]
WOS关键词	MECHANOCHROMIC LUMINESCENCE ; CRYSTAL-STRUCTURE ; THERMOCHROMIC-LUMINESCENCE ; COORDINATION-NUMBER ; IODIDE CLUSTERS ; COMPLEXES ; CATION ; METAL ; CH3NH3PBI3 ; PEROVSKITE
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000468364500043
资助机构	National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Dalian Institute of Chemical Physics ; Dalian Institute of Chemical Physics
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171865]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Feng, Liang
作者单位	1.Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China 4.Chinese Univ Hong Kong, Ctr Sci Modeling & Computat, Shatin, Hong Kong, Peoples R China
推荐引用方式 GB/T 7714	Chen, Shuqin,Gao, Jianmei,Chang, Junyu,et al. Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(19):17513-17520.
APA	Chen, Shuqin.,Gao, Jianmei.,Chang, Junyu.,Li, Yanqi.,Huangfu, Changxin.,...&Feng, Liang.(2019).Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials.ACS APPLIED MATERIALS & INTERFACES,11(19),17513-17520.
MLA	Chen, Shuqin,et al."Family of Highly Luminescent Pure Ionic Copper(I) Bromide Based Hybrid Materials".ACS APPLIED MATERIALS & INTERFACES 11.19(2019):17513-17520.