Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons

doi:10.1002/anie.201510872

	Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons
	Li, Yanbang 2; Gan, Liangbing 1,2; Xu, Dan 2
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2016-02-12
卷号	55 期号:7 页码:2483-2487
关键词	Amination Conjugation Fullerenes Nucleophilic Addition X-ray Diffraction
ISSN号	1433-7851
DOI	10.1002/anie.201510872
文献子类	Article
英文摘要	Secondary aliphatic amines add to a pole pentagon of [70] fullerene in the presence of N-fluorobenzenesulfonimide to form cyclopentadienyl-type adducts, C-70(NSO2Ph)( NR1R2) 4 (1), which can be converted into analogous C-70 derivatives such as C-70(NHSO2Ph)(NHTol) 5 (2). Further addition reactions of either 1 or 2 take place selectively at the opposite pole pentagon of the C-70 'cage, thus forming curved p systems with a reduced number of p electrons, and the products include a dodecakis-adduct with a Vogtle belt motif.
WOS关键词	FULLERENE CHEMISTRY ; SOLAR-CELLS ; C-60 ; REGIOCHEMISTRY ; AMINE ; FUNCTIONALIZATION ; DERIVATIVES ; CYCLOPHANE ; COMPLEXES ; ADDITIONS
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000369970500033
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/171250]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Gan, Liangbing
作者单位	1.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Li, Yanbang,Gan, Liangbing,Xu, Dan. Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(7):2483-2487.
APA	Li, Yanbang,Gan, Liangbing,&Xu, Dan.(2016).Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(7),2483-2487.
MLA	Li, Yanbang,et al."Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.7(2016):2483-2487.